publication . Article . Other literature type . 2010

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials

Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.;
Open Access
  • Published: 01 Jan 2010
Abstract
Anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2, and ThCl4(THF)3.5 have been easily accessed from inexpensive, commercially available reagents under mild conditions and serve as excellent precursors to a variety of thorium(IV) halide, alkoxide, amide and organometallic compounds.
Subjects
free text keywords: Materials Chemistry, Electronic, Optical and Magnetic Materials, General Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Catalysis, Thorium, chemistry.chemical_element, chemistry, Inorganic chemistry, Alkoxide, chemistry.chemical_compound, 1,4-Dioxane, Anhydrous, Group 2 organometallic chemistry, Organic chemistry, Tetrachloride, Amide, Halide
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publication . Article . Other literature type . 2010

Convenient access to the anhydrous thorium tetrachloride complexes ThCl4(DME)2, ThCl4(1,4-dioxane)2 and ThCl4(THF)3.5 using commercially available and inexpensive starting materials

Cantat, Thibault; Scott, Brian L.; Kiplinger, Jaqueline L.;