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Higher-order interfiber interactions in the self-assembly of benzene-1,3,5-tricarboxamide-based peptides in water†

Zagorodko, Oleksandr; Melnyk, Tetiana; Rogier, Olivier; Nebot, Vicent J.; Vicent, María J.;
Open Access
Abstract
<p>Mimicking the complexity of biological systems with synthetic supramolecular materials requires a deep understanding of the relationship between the structure of the molecule and its self-assembly pattern. Herein, we report a series of water-soluble benzene-1,3,5-tricarboxamide-based di- and tripeptide derivatives modified with small non-bulky terminal amine salt to induce self-assembly into twisted one-dimensional higher-order nanofibers. The morphology of nanofibers strongly depends on the nature, order, and quantity of amino acids in the short peptide fragments and vary from simple cylindrical to complex helical. From observations of several fiber-splittin...
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Funded by
EC| MyNano
Project
MyNano
Towards the design of Personalised Polymer-based Combination Nanomedicines for Advanced Stage Breast Cancer Patients
  • Funder: European Commission (EC)
  • Project Code: 648831
  • Funding stream: H2020
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