A General, Rhodium-Catalyzed, Synthesis of Deuterated Boranes and N-Methyl Polyaminoboranes

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Colebatch, Annie L.; Hawkey Gilder, Benjamin W.; Whittell, George R.; Oldroyd, Nicola L.; Manners, Ian; Weller, Andrew S.;
(2018)

<p>The rhodium complex [Rh(Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>PPh<sub>2</sub>)(η<sup>6</sup>-FC<sub>6</sub>H<sub>5</sub>)][BAr<sup>F</sup> <sub>4</sub>], 2, catalyzes BH/BD exchange between D<sub>2</sub> and the boranes H<sub>3</sub>B⋅NMe<sub>3</su... View more
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