publication . Doctoral thesis . 2015

Activation of Chalcogens and Chalcogenides at Reactive Uranium Centers

Franke, Sebastian;
Open Access English
  • Published: 01 Jan 2015
  • Country: Germany
The coordination chemistry of uranium has experienced a tremendous recent increase of interest within the last three decades, likely due to the fact that complexes of trivalent uranium can effectively engage activation and functionalization of small molecules, such as carbon monoxide (CO), carbon dioxide (CO2), dinitrogen (N2), or dioxygen (O2). Many small molecules are of great biochemical and industrial relevance, but their thermodynamical stability requires high pressures and temperatures for them to undergo any reactions. In contrast, uranium(III) complexes can often react with these chemically inert molecules under much milder conditions. The high reactivit...
free text keywords: Uran ; Komplexe ; Koordinationslehre ; Spektroskopie ; Reaktivität ; Molekülstruktur ; Chalkogene; Chalkogenide; Chalcogene; Chalcogenide, Naturwissenschaftliche Fakultät, ddc:546
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