Iodide-photocatalyzed reduction of carbon dioxide to formic acid with thiols and hydrogen sulfide

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Berton, Mateo Otao; Mello, Rossella C. C.; González Núñez, María Elena;

The photolysis of iodide anions promotes the reaction of carbon dioxide with hydrogen sulfide or thiols to quantitatively yield formic acid and sulfur or disulfides. The reaction proceeds in acetonitrile and aqueous solutions, at atmospheric pressure and room temperatur... View more
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