publication . Preprint . 2018

Synthesis of carbonate esters by carboxymethylation using NaAlO2 as a highly active heterogeneous catalyst

Ramesh, Sreerangappa; Indukuri, Kiran; Riant, Olivier; Debecker, Damien;
Open Access English
  • Published: 01 May 2018
Abstract
<p>Sodium aluminate is presented as a highly active heterogeneous catalyst able to convert a range of alcohols into the corresponding mixed carbonate esters, in high yield and under green conditions. The reaction is carried out using dimethyl carbonate both as a reactant and solvent, at 90°C. Allylic, aliphatic and aromatic alcohols are converted in good yields. The solid catalyst is shown to be truly heterogeneous, resistant to leaching, and recyclable. </p>
Subjects
mesheuropmc: inorganic chemicalsorganic chemicals
free text keywords: dimethyl carbonate, sodium aluminate, asymmetric carbonate esters, carboxymethylation, Spray drying
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Preprint . 2018
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