publication . Article . 1992

[(η5-Cp)2Sn(μ-η5-Cp)Na · PMDETA], a Compound with a Trigonal-Planar “Paddle Wheel” Triorganostannate Ion†

Davidson, Matthew G.; Stalke, Dietmar; Wright, Dominic S.;
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  • Published: 01 Jan 1992 Journal: Angewandte Chemie International Edition in English, volume 31, pages 1,226-1,227 (issn: 0570-0833, eissn: 1521-3773, Copyright policy)
  • Publisher: Wiley
  • Country: Germany
Abstract
An organotin(II) anion with three 5-Cp ligands and a p. atom in a trigonal-planar environment are found in the title compound 1 (see diagram), obtained from the reaction of CpNa, [Cp2Sn], and PMDETA (mol ratio 1:1:1). This [Cp3Sn]- ion is linked to the Na+ ion by a -5-Cp bridge. Compound 1 is a polymeric array in the solid state due to intermolecular C(H) Na interactions. PMDETA = (Me2NCH2CH2)2NMe. peerReviewed
Subjects
free text keywords: anorganische Chemie, 540, Ligand, Molecule, Ion, Stereochemistry, Solid-state, Trigonal planar molecular geometry, Paddle wheel, Crystallography, Tin, chemistry.chemical_element, chemistry, Inorganic chemistry
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publication . Article . 1992

[(η5-Cp)2Sn(μ-η5-Cp)Na · PMDETA], a Compound with a Trigonal-Planar “Paddle Wheel” Triorganostannate Ion†

Davidson, Matthew G.; Stalke, Dietmar; Wright, Dominic S.;