Conformational cooling and conformation selective aggregation in dimethyl sulfite isolated in solid rare gases

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Borba, Ana; Gómez-Zavaglia, Andrea; Fausto, Rui;
(2006)
  • Subject: Matrix isolation FTIR Spectroscopy | Dimethyl sulfite | Conformation selective aggregation | Conformational cooling
Dimethyl sulfite has three conformers of low energy, GG, GT and GG0, which have significant populations in the gas phase at room temperature. According to theoretical predictions, the GT and GG0 conformers are higher in energy than the GG conformer by 0.83 and 1.18 kJ m... View more
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