publication . Article . 2017

Urea dimethacrylates functionalized with bisphosphonate/bisphosphonic acid for improved dental materials

Güven, Melek Naz; Guven, Melek Naz; Akyol, Ece; Duman, Fatma Demir; Acar, Havva Yağcı; Acar, Havva Yagci; Karahan, Özlem; Karahan, Ozlem; Avcı, Duygu; Avci, Duygu;
Restricted
  • Published: 01 Oct 2017 Journal: Journal of Polymer Science Part A: Polymer Chemistry, volume 55, pages 3,195-3,204 (issn: 0887-624X, Copyright policy)
  • Publisher: Wiley
  • Country: Yemen
Abstract
Incorporation of bisphosphonate/bisphosphonic acid groups in dental monomer structures should increase interaction of these monomers with dental tissue as these groups have strong affinity for hydroxyapatite. Therefore, new urea dimethacrylates functionalized with bisphosphonate (1a, 1b) and bisphosphonic acid (2a, 2b) groups are synthesized and evaluated for dental applications. Monomers 1a and 1b are synthesized from 2‐isocyanatoethyl methacrylate (IEM) and two bisphosphonated amines (BPA1 and BPA2), prepared as reported elsewhere. Selective dealkylation of the bisphosphonate ester groups of 1a and 1b using trimethylsilyl bromide (TMSBr) gives monomers (2a and...
Subjects
free text keywords: Alkylation, Phosphate, chemistry.chemical_compound, chemistry, Methacrylate, Organic chemistry, Photopolymer, Raman spectroscopy, symbols.namesake, symbols, Polymer chemistry, Urea, Monomer, X-ray photoelectron spectroscopy, QD Chemistry
Related Organizations
Powered by OpenAIRE Open Research Graph
Any information missing or wrong?Report an Issue
publication . Article . 2017

Urea dimethacrylates functionalized with bisphosphonate/bisphosphonic acid for improved dental materials

Güven, Melek Naz; Guven, Melek Naz; Akyol, Ece; Duman, Fatma Demir; Acar, Havva Yağcı; Acar, Havva Yagci; Karahan, Özlem; Karahan, Ozlem; Avcı, Duygu; Avci, Duygu;