publication . Article . 2008

Flash-Point prediction for binary partially miscible aqueous-organic mixtures

Horng-Jang Liaw; Chien Tsun Chen; Vincent Gerbaud;
Open Access English
  • Published: 01 Sep 2008
  • Publisher: Elsevier
  • Country: France
Abstract Flash point is the most important variable used to characterize fire and explosion hazard of liquids. Herein, partially miscible mixtures are presented within the context of liquid–liquid extraction processes and heterogeneous distillation processes. This paper describes development of a model for predicting the flash point of binary partially miscible mixtures of aqueous–organic system. To confirm the predictive efficiency of the derived flash points, the model was verified by comparing the predicted values with the experimental data for the studied mixtures: water + 1 - butanol ; water + 2 - butanol ; water + isobutanol ; water + 1 - pentanol ; and, w...
Persistent Identifiers
free text keywords: Génie chimique, Flash point, Prediction, Partially miscible mixtures, Aqueous-organic solution, Vapor-liquid-liquid equilibrium, Binary number, Butanol, chemistry.chemical_compound, chemistry, Chemical process, Distillation, law.invention, law, Octane, Flash point, Aqueous solution, Thermodynamics, Liquid–liquid extraction
26 references, page 1 of 2

Abrams, D.S., Prausnitz, J.M., 1975. Statistical thermodynamics of liquid mixtures: new expression for the excess Gibbs energy of partly or completely miscible systems. A.I.Ch.E Journal 21, 116-128.

Affens, W.A., McLaren, G.W., 1972. Flammability properties of hydrocarbon solutions in air. Journal of Chemical and Engineering Data 17, 482-488.

ASTM D 56, 1999. Standard test method for flash point by Tag closed tester. American Society for Testing and Materials, West Conshohocken, PA, USA.

Bohnet, M. et al., 2007. Ullmann's Encyclopedia of Industrial Chemistry. Wiley InterScience (John Wiley & Sons), USA.

Catoire, L., Paulmier, S., 2006. Estimation of closed cup flash points of combustible solvent blends. Journal of Physical and Chemical Reference Data 35, 9-14. [OpenAIRE]

CCPS/AIChE, 1993. Guidelines for Engineering Design for Process Safety. American Institute of Chemical Engineers, New York, USA.

Crowl, D.A., Louvar, J.F., 2002. Chemical Process Safety: Fundamentals with Applications. Prentice Hall PTR, New Jersey, USA.

DOT, 2004. Shippers - General Requirements for Shipments and Packagings, Class3 - Assignment of Packing Group, 49CFR173.121. National Archives and Records Administration, USA.

Fisher Scientific, 2008. 〈〉.

Freepatentsonline, 2008. 〈〉.

Garland, R.W., Malcolm, M.O., 2002. Evaluating vent manifold inerting requirements: flash point modeling for organic acid-water mixtures. Process Safety Progress 21, 254-260.

Gmehling, J., Onken, U., Arlt, W., 1980. Vapor-Liquid Equilibrium Data Collection, Part 6a. DECHEMA, Frankfurt, Germany.

Gmehling, J., Onken, U., Arlt, W., 1981. Vapor-Liquid Equilibrium Data Collection, Part 1a. DECHEMA, Frankfurt, Germany.

Gόra, M., Wiśniewska-Gocłowska, B., Mączyński, A., 2006. Recommended liquid-liquid equilibrium data. part 4. 1-akanol-water systems. Journal of Physical and Chemical Reference Data 35, 1391-1414.

Klauck, M., Grenner, A., Schmelzer, J., 2006. Liquid-liquid(-liquid) equilibria in ternary systems of water + cyclohexylamine + aromatic hydrocarbon (toluene or propylbenzene) or aliphatic hydrocarbon (heptane or octane). Journal of Chemical and Engineering Data 51, 1043-1050. [OpenAIRE]

26 references, page 1 of 2
Any information missing or wrong?Report an Issue