Hydrogen activation with perfluorinated organoboranes: 1,2,3- tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene
Houghton, Adrian Y.
Piers, Warren E.
- Publisher: RSC Publications
organoboraanit | vedyn aktivointi | fluorattu boraindeeni | organoboron compounds | hydrogen activation | perfluorinated boraindene
The perfluorinated boraindene 3 was synthesized and fully characterized. Both computational and crystallographic data show that 3 is antiaromatic. Compound 3 was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalys...