Pot-Economy Autooxidative Condensation of 2-Aryl-2-lithio-1,3-dithianes

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Vale, João R.; Rimpiläinen, Tatu; Sievänen, Elina; Rissanen, Kari; Afonso, Carlos A. M.; Candeias, Nuno R.;
(2018)
  • Publisher: American Chemical Society
  • Subject: organometalliyhdisteet | hapettuminen | litium | autooxidative condensation | organometallic compounds | oxidation (passive) | lithium

The autoxidative condensation of 2-aryl-2-lithio-1,3-dithianes is here reported. Treatment of 2-aryl-1,3-dithianes with n-BuLi in the absence of any electrophile leads to condensation of three molecules of 1,3-dithianes and formation of highly functionalized α-thioether... View more
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