publication . Part of book or chapter of book . 2008

Raman spectroscopy, ab-initio model calculations, and conformational, equilibria in ionic liquids

Rolf W. Berg;
Open Access
  • Published: 09 Oct 2008
  • Country: Denmark
Abstract
A review of the recent developments in the study and understanding of room temperature ionic liquids are given. An intimate picture of how and why these liquids are not crystals at ambient conditions is attempted, based on evidence from crystallographical results combined with vibrational spectroscopy and ab-initio molecular orbital calculations. A discussion is given, based mainly on some recent FT- Raman spectroscopic results on the model ionic liquid system of 1-butyl-3-methyl-imidazolium ([C4C1Im]+X-) salts. The rotational isomerism of the [C4C1Im]+ cation is described: the presence of anti and gauche conformational forms that has been elucidated in remarkab...
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http://orbit.dtu.dk/ws/files/4...
Part of book or chapter of book
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https://orbit.dtu.dk/en/public...
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http://dx.doi.org/10.1201/9781...
Part of book or chapter of book . 2008
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