publication . Other literature type . Article . 2014

Catalysis engineering of bifunctional solids for the one-step synthesis of liquid fuels from syngas: A review

Sina Sartipi; Michiel Makkee; Freek Kapteijn; Jorge Gascon;
  • Published: 09 Jan 2014
  • Publisher: Royal Society of Chemistry (RSC)
  • Country: Netherlands
Abstract
The combination of acidic zeolites and Fischer–Tropsch synthesis (FTS) catalysts for one-step production of liquid fuels from syngas is critically reviewed. Bifunctional systems are classified by the proximity between FTS and acid functionalities on three levels: reactor, catalyst particle, and active phase. A thorough analysis of the published literature on this topic reveals that efficiency in the production of liquid fuels correlates well with the proximity of FTS and acid sites. Moreover, possible side reactions over the FTS metal, including direct CO hydrogenation and hydrocarbon hydrogenolysis, are addressed. The contribution of these side reactions should...
Subjects
free text keywords: Gold for Gold, Open Access, Catalysis, Inorganic chemistry, Syngas, Chemistry, One-Step, Organic chemistry, Bifunctional, chemistry.chemical_compound, Particle, Hydrocarbon, chemistry.chemical_classification, Hydrogenolysis, Zeolite
114 references, page 1 of 8

1 S. T. Sie, M. M. G. Senden and H. M. H. Van Wechem, Catal. Today, 1991, 8, 371-394.

2 A. de Klerk and E. Furimsky, Catalysis in the Refining of Fischer-Tropsch Syncrude, RSC Publishing, Cambridge, UK, 2010. [OpenAIRE]

3 M. J. A. Tijmensen, A. P. C. Faaij, C. N. Hamelinck and M. R. M. Van Hardeveld, Biomass Bioenergy, 2002, 23, 129-152.

4 http://www.compactgtl.com/.

5 http://www.velocys.com/.

6 C. Kibby, K. Jothimurugesan, T. Das, H. S. Lacheen, T. Rea and R. J. Saxton, Catal. Today, 2013, 215, 131-141.

7 Q. Zhang, K. Cheng, J. Kang, W. Deng and Y. Wang, ChemSusChem, 2014, DOI: 10.1002/cssc.201300797.

8 V. U. S. Rao, R. J. Gormley, A. Shamsi, T. R. Petrick, J. M. Stencel, R. R. Schehl, R. D. H. Chi and R. T. Obermyer, J. Mol. Catal., 1985, 29, 271-283.

9 V. Udaya, S. Rao and R. J. Gormley, Catal. Today, 1990, 6, 207-234.

10 C. A. Chanenchuk, I. C. Yates and C. N. Satterfield, Energy Fuels, 1991, 5, 847-855. [OpenAIRE]

11 D. Vervloet, F. Kapteijn, J. Nijenhuis and J. R. Van Ommen, Catal. Sci. Technol., 2012, 2, 1221-1233.

12 O. O. James, A. M. Mesubi, T. C. Ako and S. Maity, Fuel Process. Technol., 2010, 91, 136-144.

13 C. Zeng, J. Sun, G. Yang, I. Ooki, K. Hayashi, Y. Yoneyama, A. Taguchi, T. Abe and N. Tsubaki, Fuel, 2013, 112, 140-144.

14 M. E. Dry, Catal. Today, 2002, 71, 227-241.

15 A. Y. Khodakov, W. Chu and P. Fongarland, Chem. Rev., 2007, 107, 1692-1744.

114 references, page 1 of 8
Abstract
The combination of acidic zeolites and Fischer–Tropsch synthesis (FTS) catalysts for one-step production of liquid fuels from syngas is critically reviewed. Bifunctional systems are classified by the proximity between FTS and acid functionalities on three levels: reactor, catalyst particle, and active phase. A thorough analysis of the published literature on this topic reveals that efficiency in the production of liquid fuels correlates well with the proximity of FTS and acid sites. Moreover, possible side reactions over the FTS metal, including direct CO hydrogenation and hydrocarbon hydrogenolysis, are addressed. The contribution of these side reactions should...
Subjects
free text keywords: Gold for Gold, Open Access, Catalysis, Inorganic chemistry, Syngas, Chemistry, One-Step, Organic chemistry, Bifunctional, chemistry.chemical_compound, Particle, Hydrocarbon, chemistry.chemical_classification, Hydrogenolysis, Zeolite
114 references, page 1 of 8

1 S. T. Sie, M. M. G. Senden and H. M. H. Van Wechem, Catal. Today, 1991, 8, 371-394.

2 A. de Klerk and E. Furimsky, Catalysis in the Refining of Fischer-Tropsch Syncrude, RSC Publishing, Cambridge, UK, 2010. [OpenAIRE]

3 M. J. A. Tijmensen, A. P. C. Faaij, C. N. Hamelinck and M. R. M. Van Hardeveld, Biomass Bioenergy, 2002, 23, 129-152.

4 http://www.compactgtl.com/.

5 http://www.velocys.com/.

6 C. Kibby, K. Jothimurugesan, T. Das, H. S. Lacheen, T. Rea and R. J. Saxton, Catal. Today, 2013, 215, 131-141.

7 Q. Zhang, K. Cheng, J. Kang, W. Deng and Y. Wang, ChemSusChem, 2014, DOI: 10.1002/cssc.201300797.

8 V. U. S. Rao, R. J. Gormley, A. Shamsi, T. R. Petrick, J. M. Stencel, R. R. Schehl, R. D. H. Chi and R. T. Obermyer, J. Mol. Catal., 1985, 29, 271-283.

9 V. Udaya, S. Rao and R. J. Gormley, Catal. Today, 1990, 6, 207-234.

10 C. A. Chanenchuk, I. C. Yates and C. N. Satterfield, Energy Fuels, 1991, 5, 847-855. [OpenAIRE]

11 D. Vervloet, F. Kapteijn, J. Nijenhuis and J. R. Van Ommen, Catal. Sci. Technol., 2012, 2, 1221-1233.

12 O. O. James, A. M. Mesubi, T. C. Ako and S. Maity, Fuel Process. Technol., 2010, 91, 136-144.

13 C. Zeng, J. Sun, G. Yang, I. Ooki, K. Hayashi, Y. Yoneyama, A. Taguchi, T. Abe and N. Tsubaki, Fuel, 2013, 112, 140-144.

14 M. E. Dry, Catal. Today, 2002, 71, 227-241.

15 A. Y. Khodakov, W. Chu and P. Fongarland, Chem. Rev., 2007, 107, 1692-1744.

114 references, page 1 of 8
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publication . Other literature type . Article . 2014

Catalysis engineering of bifunctional solids for the one-step synthesis of liquid fuels from syngas: A review

Sina Sartipi; Michiel Makkee; Freek Kapteijn; Jorge Gascon;