publication . Article . 2016

Insulator-protected mechanically controlled break junctions for measuring single-molecule conductance in aqueous environments

Muthusubramanian, N.; Galan, E.; Maity, C.; Eelkema, R.; Grozema, F.C.; van der Zant, H.S.J.;
Open Access English
  • Published: 04 Jul 2016
  • Country: Netherlands
Abstract
<p>We present a method to fabricate insulated gold mechanically controlled break junctions (MCBJ) by coating the metal with a thin layer of aluminum oxide using plasma enhanced atomic layer deposition. The Al<sub>2</sub>O<sub>3</sub> thickness deposited on the MCBJ devices was varied from 2 to 15 nm to test the suppression of leakage currents in deionized water and phosphate buffered saline. Junctions coated with a 15 nm thick oxide layer yielded atomically sharp electrodes and negligible conductance counts in the range of 1 to 10<sup>-4</sup> G<sub>0</sub> (1 G<sub>0</sub> = 77 μS), where single-molecule conductances are commonly observed. The insulated devices...
Funded by
EC| MOLESCO
Project
MOLESCO
MOLECULAR-SCALE ELECTRONICS: Concepts, Contacts and Stability "MOLESCO"
  • Funder: European Commission (EC)
  • Project Code: 606728
  • Funding stream: FP7 | SP3 | PEOPLE
Download from
TU Delft Repository
Article . 2016
Provider: NARCIS
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