Enantioselective preparation of 1,3-dithiane 1-oxides by asymmetric oxidation of 1,3-dithianes bearing a chiral auxiliary

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Yoshihiko, Watanabe; Yojiro, Ono; Shigefumi, Hayashi; Yoshio, Ueno; Takeshi, Toru;
(1996)
  • Publisher: Royal Society of Chemistry
  • Journal: Journal of the Chemical Society. Perkin transactions 1 : organic and bio-organic chemistry.,volume 1,996,issue 15,pages1,879-1,885 (issn: 0300922x)
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Oxidation of 1,3-dithianes bearing a chiral auxiliary derived from (+) or (-)-camphor or diacetone D-(+)-glucose by the Sharpless reagent [Ti(OPi)4-diethyl L-(+)- or D-(-)-tartrate-ButOOH] affords, with high stereoselectivity, the monosulfoxides in good to excellent yie... View more
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