Synthesis of 1,1-Diborylalkenes through a Bronsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

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Morinaga, Akira; Nagao, Kazunori; Ohmiya, Hirohisa; Sawamura, Masaya;
(2015)
  • Publisher: Wiley-Blackwell
  • Journal: Angewandte chemie-international edition,volume 54,issue 52,pages15,859-15,862 (issn: 1433-7851)
  • Publisher copyright policies & self-archiving
  • Subject: boration | Bronsted bases | diborylalkenes | organocatalysis | synthetic methods

A method for the synthesis of 1,1-diborylalkenes through a Bronsted base catalyzed reaction between terminal alkynes and bis(pinacolato)diboron has been developed. The procedure allows direct synthesis of functionalized 1,1-diborylalkenes from various terminal alkynes i... View more
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