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Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis

descriptionPublicationkeyboard_double_arrow_right Article 23 Jun 2020 Belgium Publisher:American Chemical Society (ACS)Journal:ACS Catalysis, volume 10, pages 8,765-8,779 (issn: 2155-5435, eissn: 2155-5435,

Authors: Karthik Gadde; Pieter Mampuys; Andrea Guidetti; H. Y. Vincent Ching; Wouter A. Herrebout; Sabine Van Doorslaer; Kourosch Abbaspour Tehrani; +1 Authors

doi: 10.1021/acscatal.0c02159

handle: 10067/1704230151162165141

Thiosulfonylation of Unactivated Alkenes with Visible-Light Organic Photocatalysis

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Abstract

A metal-free method for the vicinal thiosulfonylation of unactivated alkenes with thiosulfonates using 9-mesityl-10-methylacridinium perchlorate as the photo-organocatalyst with visible-light irrad...

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Belgium

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University of Antwerp
Belgium

Keywords

Chemistry, Visible-light photocatalysis Organic photocatalyst Thiosulfonates Difunctionalization Energy Transfer

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Development of sustainable catalytic methods : aza-cope rearrangement of homoallylamines and thiosulfonylation of alkenes
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