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ChemInform Abstract: Ti2GaC, Ti4GaC3and Cr2GaC - Synthesis, Crystal Growth and Structure Analysis of Ga-Containing MAX-Phases Mn+1GaCnwith M: Ti, Cr and n = 1, 3.
Copyright policy )ChemInform Abstract: Ti2GaC, Ti4GaC3and Cr2GaC - Synthesis, Crystal Growth and Structure Analysis of Ga-Containing MAX-Phases Mn+1GaCnwith M: Ti, Cr and n = 1, 3.
Single crystals of Ga-containing MAX-phases Ti{sub 2}GaC, Ti{sub 4}GaC{sub 3}, and Cr{sub 2}GaC were grown from a metallic melt generated by an excess of Ga. This technique allows the crystal growth at different temperatures to control the product distribution. Compounds developed were Ti{sub 2}GaC and TiC at 1500 deg. C, and Ti{sub 2}GaC and Ti{sub 4}GaC{sub 3} at 1300 deg. C. Crystal structures were refined from single crystal data. Ti{sub 2}GaC and Cr{sub 2}GaC were previously known, and belong to the Cr{sub 2}AlC type as well as the solid solutions V{sub 2}Ga{sub 1-x}Al{sub x}C and Cr{sub 2}Ga{sub 1-x}Al{sub x}C. Ti{sub 4}GaC{sub 3} is one of the few 413-phases (P6{sub 3}/mmc, a=3.0690(4) A, c=23.440(5) A) and the first Ga-containing representative. The crystal structures of MAX-phases are intergrowths of layers of an intermetallic MGa in a hexagonal stacking sequence with carbidic layers (MC){sub n} of the NaCl type. The thickness of the layer depends from the value of n. The results of the structure refinements also demonstrate that also the structural details follow this description. - Graphical abstract: Single crystals of Ga-containing MAX-Phases (TiC){sub n}(TiGa) (n=1, 3) were grown from a metallic melt including and characterised by X-ray diffraction. Ti{sub 4}GaC{sub 3}more » is one of the few 413-phase and the first containing Ga.« less
- University of Toronto Canada
- University of Freiburg Germany
Microsoft Academic Graph classification: Metal Crystallography Chemistry visual_art visual_art.visual_art_medium Intermetallic Crystal growth Crystal structure MAX phases Type (model theory) Single crystal Solid solution
General Medicine
General Medicine
Microsoft Academic Graph classification: Metal Crystallography Chemistry visual_art visual_art.visual_art_medium Intermetallic Crystal growth Crystal structure MAX phases Type (model theory) Single crystal Solid solution
citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).0 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average citations This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).0 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Average influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Average impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Average
Popularity provided by BIP!- University of Toronto Canada
- University of Freiburg Germany
Single crystals of Ga-containing MAX-phases Ti{sub 2}GaC, Ti{sub 4}GaC{sub 3}, and Cr{sub 2}GaC were grown from a metallic melt generated by an excess of Ga. This technique allows the crystal growth at different temperatures to control the product distribution. Compounds developed were Ti{sub 2}GaC and TiC at 1500 deg. C, and Ti{sub 2}GaC and Ti{sub 4}GaC{sub 3} at 1300 deg. C. Crystal structures were refined from single crystal data. Ti{sub 2}GaC and Cr{sub 2}GaC were previously known, and belong to the Cr{sub 2}AlC type as well as the solid solutions V{sub 2}Ga{sub 1-x}Al{sub x}C and Cr{sub 2}Ga{sub 1-x}Al{sub x}C. Ti{sub 4}GaC{sub 3} is one of the few 413-phases (P6{sub 3}/mmc, a=3.0690(4) A, c=23.440(5) A) and the first Ga-containing representative. The crystal structures of MAX-phases are intergrowths of layers of an intermetallic MGa in a hexagonal stacking sequence with carbidic layers (MC){sub n} of the NaCl type. The thickness of the layer depends from the value of n. The results of the structure refinements also demonstrate that also the structural details follow this description. - Graphical abstract: Single crystals of Ga-containing MAX-Phases (TiC){sub n}(TiGa) (n=1, 3) were grown from a metallic melt including and characterised by X-ray diffraction. Ti{sub 4}GaC{sub 3}more » is one of the few 413-phase and the first containing Ga.« less