publication . Article . 2016

Carbon nanotubes functionalized by salts containing stereogenic heteroatoms as electrodes in their battery cells

Damian Kulawik; Józef Drabowicz; Tomasz Girek; Wojciech Ciesielski; Volodymyr Pavlyuk; Magdalena Pyzalska; Sandra Zdanowska;
Open Access
  • Published: 01 Dec 2016 Journal: Polish Journal of Chemical Technology, volume 18, pages 22-26 (eissn: 1899-4741, Copyright policy)
  • Publisher: Walter de Gruyter GmbH
Abstract
<jats:title>Abstract</jats:title> <jats:p>This paper concentrates on electrochemical properties of groups of multi-walled carbon nanotubes (MWCNT) functionalized with substituents containing a stereogenic heteroatom bonded covalently to the surface of the carbon nanotube. This system was tested in Swagelok-type cells. The cells comprised a system (functionalized CNT with salts containing S and P atoms) with a working electrode, microfiber separators soaked with electrolyte solution, and a lithium foil counter/reference (commercial LiCoO<jats:sub>2</jats:sub>) electrode. The electrolyte solution was 1 M LiPF<jats:sub>6</jats:sub> in propylene carbonate. Using sta...
Subjects
free text keywords: multi-walled carbon nanotubes (MWCNT), battery, bromination, charge transfer, X-ray spectroscopy, electronic structure, Chemistry, QD1-999, Battery (electricity), Industrial chemistry, Halogenation, Organic chemistry, Stereocenter, Carbon nanotube, law.invention, law, Polymer chemistry, Electrode, Heteroatom, Materials science, Selective chemistry of single-walled nanotubes
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