publication . Article . 2017

Hydrogenation of Phenol over Pt/CNTs: The Effects of Pt Loading and Reaction Solvents

Feng Li; Bo Cao; Wenxi Zhu; Hua Song; Keliang Wang; Cuiqin Li;
Open Access
  • Published: 08 May 2017 Journal: Catalysts, volume 7, page 145 (eissn: 2073-4344, Copyright policy)
  • Publisher: MDPI AG
Abstract
Carbon nanotubes (CNTs)-supported Pt nanoparticles were prepared with selective deposition of Pt nanoparticles inside and outside CNTs (Pt–in/CNTs and Pt–out/CNTs). The effects of Pt loading and reaction solvents on phenol hydrogenation were investigated. The Pt nanoparticles in Pt–in/CNTs versus Pt–out/CNTs are smaller and better dispersed. The catalytic activity and reuse stability toward phenol hydrogenation both improved markedly. The dichloromethane–water mixture as the reaction solvent, compared with either pure medium, decreased the catalytic activity toward phenol hydrogenation and selectivity of cyclohexanone over Pt–in/CNTs, but significantly improved ...
Subjects
free text keywords: Chemistry, Nanoparticle, Catalysis, Solvent, Organic chemistry, Carbon nanotube, law.invention, law, Selectivity, Cyclohexanone, chemistry.chemical_compound, Phenol, Inorganic chemistry, Deposition (law), Pt/CNTs, hydrogenation, loading method, reaction solvent, Chemical technology, TP1-1185, QD1-999
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publication . Article . 2017

Hydrogenation of Phenol over Pt/CNTs: The Effects of Pt Loading and Reaction Solvents

Feng Li; Bo Cao; Wenxi Zhu; Hua Song; Keliang Wang; Cuiqin Li;