Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ علوم و تکنولوژی پلیم...arrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
addClaim

This Research product is the result of merged Research products in OpenAIRE.

You have already added 0 works in your ORCID record related to the merged Research product.
addClaim

This Research product is the result of merged Research products in OpenAIRE.

You have already added 0 works in your ORCID record related to the merged Research product.

Mechanical Properties and Kinetics of Thermal Degradation of Bioplastics based on Straw Cellulose and Whole Wheat Flour

Authors: Hesam Omrani fard; Ahmad Ghazanfari Moghaddam; Mohsen Shamsi; S. Ahmad Ataei;

Mechanical Properties and Kinetics of Thermal Degradation of Bioplastics based on Straw Cellulose and Whole Wheat Flour

Abstract

During the past two decades the use of bioplastics, as a suitable alternative to petroleum-based plastics, has attracted researchers' attention to a great extent. In this study, the whole wheat four and straw cellulose at different proportions were mixed with glycerol and bioplastics sheets were obtained by a press type molding machine. The mechanical properties of samples were examined on compositions prepared by whole wheat weight in three proportions of 70, 60 and 50% and the cellulose in three proportions 75, 70 and 65%. The tensile tests on the samples indicated that with lowering proportions of both four and cellulose, the modulus of elasticity and tensile strength of the bioplastics dropped as well. The maximum modulus of elasticity achieved for the four and cellulose compositions were 12.5, and 8.6 MPa, and the maximum tensile strengths were 878 and 202 kPa, respectively. The TGA tests indicated that the bioplastics prepared from whole wheat four showed higher temperatures of thermal degradation. The activation energies calculated for the four and cellulose bioplastics, as estimated by Arrhenius type equation, were 133.0 and 63.8 kJ/mol, respectively.

Keywords

TP1080-1185, straw cellulose, thermal degradation, Polymers and polymer manufacture, mechanical properties, whole wheat flour, bioplastic

21 references, page 1 of 3

1. Siracusa V., Rocculi P., Romani S., and Dalla Rosa M., Biodegradable Polymers for Food Packaging: a Review, Trend Food Sci. Technol., 19, 634-643, 2008.

2. Sun Y. and Cheng J., Hydrolysis of Lignocellulosic Materials for Ethanol Production: a Review, Bioresou. Technol., 83, 1-11, 2002.

3. Gonzalez G.J., Partal P., Garcia M.M., and Gallegos C., Effect of Processing on the Viscoelastic; Tensile and Optical Properties of Albumen/Starch-based Bioplastics, Carbohyd. Polym., 84, 308-315, 2011.

4. Tummala P., Liu W., Drzal L.T., Mohanty A.K., and Misra M., Influence of Plasticizers on Thermal and Mechanical Proper - ties and Morphology of Soy-based Bioplastics, Ind. Eng. Chem. Res., 45, 7491-7496, 2006.

5. Salmoral E.M., Gonzalez M.E, Mariscala M.P., and Medina L.F., Comparison of Chickpea and Soy Protein Isolate and Whole Flour as Biodegradable Plastics, Indust. Crops Prod., 11, 227-236, 2000.

6. Salmoral E.M., Gonzalez M.E., and Mariscal M.P., Biodegradable Plastic Made from Bean Products, Indust. Crops Prod., 11, 217-225, 2000.

7. Almasi H., Ghanbarzadeh B., and Entezami A.A., Preparation and Study of Physical Properties of Starch CMC Biodegradable Composite Film Containing Montmorillonite Nanoparticles, Iran. J. Polym. Sci. Technnol. (In Persian), 22, 225-232, 2009. [OpenAIRE]

8. Gaspar M., Benko Zs., Dogossy G., Reczey K., and Czigany T., Reducing Water Absorption in Compostable Starch-based Plastics, Polym. Degrad. Stab., 90, 563-569, 2005.

9. Ouajai S. and Shanks R.A., Composition, Structure and Thermal Degradation of Hemp Cellulose after Chemical Treatments, Polym. Degrad. Stab., 89, 327-335, 2005. [OpenAIRE]

10. Gomez-Martinez D., Barneto A.G., Martinez I., and Partal P., Modelling of Pyrolysis and Combustion of Gluten-Glycerol based Bioplastics, Bioresou. Technol., 102, 6246-6253, 2011.

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    0
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
  • citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    0
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
    Powered byBIP!BIP!
Powered by OpenAIRE graph
Found an issue? Give us feedback
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
Average
Average
Average
moresidebar

Do the share buttons not appear? Please make sure, any blocking addon is disabled, and then reload the page.