publication . Article . 2016

Phase Separation and Elastic Properties of Poly(Trimethylene Terephthalate)-block-poly(Ethylene Oxide) Copolymers

Piesowicz, Elżbieta; Paszkiewicz, Sandra; Szymczyk, Anna;
Open Access
  • Published: 01 Jun 2016 Journal: Polymers, volume 8, page 237 (eissn: 2073-4360, Copyright policy)
  • Publisher: MDPI AG
Abstract
A series of poly(trimethylene terephthalate)-block-poly(ethylene oxide) (PTT-b-PEOT) copolymers with different compositions of rigid PTT and flexible PEOT segments were synthesized via condensation in the melt. The influence of the block length and the block ratio on the micro-separated phase structure and elastic properties of the synthesized multiblock copolymers was studied. The PEOT segments in these copolymers were kept constant at 1130, 2130 or 3130 g/mol, whereas the PTT content varied from 30 up to 50 wt %. The phase separation was assessed using differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA). The crystal structure...
Subjects
free text keywords: Thermal analysis, Thermoplastic elastomer, Copolymer, Phase (matter), Composite material, Differential scanning calorimetry, Ethylene oxide, chemistry.chemical_compound, chemistry, Small-angle X-ray scattering, Dynamic mechanical analysis, Materials science, poly(ether-ester), poly(trimethylene terephthalate), phase separation, elastic properties, Organic chemistry, QD241-441, Article
Download fromView all 3 versions
Polymers
Article . 2016
Provider: Crossref
Polymers
Article
Provider: UnpayWall
Polymers
Article . 2016
43 references, page 1 of 3

Roslaniec, Z., Pietkiewicz, D., Fakirov, S.. Synthesis and characteristics of polyester-based thermoplastic elastomers: Chemical aspects. Handbook of Thermoplastic Polyesters. 2012; Volume 1: 581-622

Liu, H., Xu, Y., Zheng, Z., Liu, D.. 1,3-Propanediol and its copolymers: Research, development and industrialization. Biotechnol. J.. 2010; 5: 1137-1148 [OpenAIRE] [PubMed] [DOI]

Kalia, S., Avérous, L.. Biodegradable and Biobased Polymers for Environmental and Biomedical Applications. 2016: 225-233

Pilla, S.. Handbook of Bioplastics and Biocomposites Engineering Applications. 2011: 422-424

Niaounakis, M.. Biopolymers: Applications and Trends. 2015: 28-30

Szymczyk, A., Nastalczyk, J., Sablong, R.J., Roslaniec, Z.. The influence of soft segment length on structure and properties of poly(trimethylene terephthalate)-block-poly(tetramethylene oxide) segmented random copolymers. Polym. Adv. Technol.. 2011; 22: 72-83 [OpenAIRE] [DOI]

Szymczyk, A.. Structure and properties of new polyester elastomers composed of poly(trimethylene terephthalate) and poly(ethylene oxide). Eur. Polym. J.. 2009; 45: 2653-2664 [OpenAIRE] [DOI]

Zhou, W., Zhang, Y., Xu, Y., Wang, P., Gao, L., Zhang, W., Ji, J.. Synthesis and characterization of bio-based poly(butylene furandicarboxylate)-b-poly(tetramethylene glycol) copolymers. Polym. Degrad. Stab.. 2014; 109: 21-26 [OpenAIRE] [DOI]

Szymczyk, A., Pawelec, I., Paszkiewicz, S.. Novel multiblock copolymers based on biopolyester from reneweable resoures. Conference Abstract Book of BIT’s, Proceedings of the 2nd Annual World Congress of Smart Materials Theme: Develop New Path of Smartness. : 568

Cohn, D., Hotovely-Salomon, A.. Biodegradable multiblock PEO/PLA thermoplastic elastomers: Molecular design and properties. Polymers. 2005; 46: 2068-2075 [OpenAIRE] [DOI]

Zhang, J., Xu, J., Wang, H., Jin, W., Li, J.. Synthesis of multiblock thermoplastic elastomers based on biodegradable poly(lactic acid) and polycaprolactone. Mater. Sci. Eng. C. 2009; 29: 889-893 [OpenAIRE] [DOI]

Fabbri, M., Gigli, M., Gamberini, R., Lotti, N., Gazzano, M., Rimini, B., Munari, A.. Hydrolysable PBS-based poly(ester urethane)s thermoplastic elastomers. Polym. Degrad. Stab.. 2014; 108: 223-231 [OpenAIRE] [DOI]

Li, S.-L., Wu, F., Wang, Y.-Z., Zeng, J.-B.. Biobased thermoplastic poly(ester urethane) elastomers consisting of poly(butylenes succinate) and poly(propylene succinate). Ind. Eng. Chem. Res.. 2015; 54: 6258-6268 [OpenAIRE] [DOI]

Webb, A.R., Yang, J., Ameer, G.A.. Biodegradable polyester elastomers in tissue engineering. Exp. Opin. Biol. Ther.. 2004; 4: 801-812 [OpenAIRE] [PubMed] [DOI]

Bettinger, C.J.. Biodegradable Elastomers for tissue engineering and cell-biomaterial interactions. Macromol. Biosci.. 2011; 11: 467-482 [OpenAIRE] [PubMed] [DOI]

43 references, page 1 of 3
Powered by OpenAIRE Open Research Graph
Any information missing or wrong?Report an Issue
publication . Article . 2016

Phase Separation and Elastic Properties of Poly(Trimethylene Terephthalate)-block-poly(Ethylene Oxide) Copolymers

Piesowicz, Elżbieta; Paszkiewicz, Sandra; Szymczyk, Anna;