Kinetics of the oxidative hydroxylation of tetraphosphorus in the presence of copper(II) chloride modified by humic (fulvo-) acid

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Zhaksyntay Kairbekov; Dina Akbayeva; Zh. Eshova; (2012)
  • Publisher: al-Farabi Kazakh National University
  • Journal: Chemical Bulletin of Kazakh National University (issn: 1563-0331, eissn: 2312-7554)
  • Related identifiers: doi: 10.15328/chemb_2012_470-74
  • Subject: white phosphorus | oxidation | oxygen | humic (fulvo-) acid | hydroxylation | phosphoric acid | kinetics | optimum conditions | Chemistry | QD1-999

<p>It was established that in mild conditions (50-70 <sup>o</sup>C, Р<sub>О</sub><sub>2</sub>= 1 atm) white phosphorus effectively is oxidized by oxygen in water-toluene solutions of copper(II) chloride modified by humic (fulvo-) acid to give mainly phosphoric acid. Hum... View more
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