publication . Article . 2015

3.2.1. Synthesis, crystal and molecular structure of catena-(bis(µ1-oxalic acid)-µ3-hydrogen oxalate-di-aqua-sodium(I)).

Olga Kovalchukova*, Sergey Aldoshin, Andrey Utenyshev, Konstantin Bogenko, Valeriy Tkachev;
Open Access English
  • Published: 01 Jul 2015 Journal: Communications in Inorganic Synthesis, volume 3, issue 2 (issn: 0719-2827, Copyright policy)
  • Publisher: Universidad de Santiago
Abstract
The crystal and molecular structure of catena-(bis(µ- oxalic acid)-µ-hydrogen oxalate-di-aqua-sodium(I)) was detected by X-Ray analysis. The compound crystallizes in the triclinic space group P-1, with a(Å) 6.2378(12); b(Å) 7,1115(14); c(Å) 10.489(2); α(°) 94.65(3); β(°) 100.12(3); γ(°) 97.78(3). The sodium cation in the title compound is eight coordinated and forms a square antiprism. It is surrounded by two molecules of oxalic acid, one hydrogen oxalate anion and one water molecule. Both oxalic acid and hydrogen oxalate anion act as polydentate bridging ligands. Centrosymmetric sodium cations are bounded by hydrogen oxalate anions through a system of H bonds i...
Subjects
free text keywords: lcsh:Science, lcsh:Q, lcsh:Chemistry, lcsh:QD1-999, lcsh:Inorganic chemistry, lcsh:QD146-197
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