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Publication . Article . 2012

Bis(3,5-di-tert-butyl-4H-1,2,4-triazol-4-amine-κN1)(nitrato-κO)silver(I) ethanol monosolvate monohydrate

Ya-Mei Liu; Jing-Huo Chen; Guang Yang; Seik Weng Ng;
Open Access
English
Published: 01 Jun 2012 Journal: Acta Crystallographica Section E, volume 68, issue 6 (issn: 1600-5368, Copyright policy )
Publisher: International Union of Crystallography
Abstract

The AgI atom in the title compound, [Ag(NO3)(C10H20N4)2]·C2H5OH·H2O, is coordinated by the N atoms of two N-heterocycles [N—Ag—N = 151.5 (1)°]; the approximately linear coordination geometry is distorted into a T-shaped geometry owing to a long Ag...Onitrate bond [2.717 (4) Å]. The N atoms of the N-heterocycles that are not involved in coordination point towards the lattice water molecule, which functions as a hydrogen-bond donor. The water molecule itself is a hydrogen-bond acceptor towards the ethanol solvent molecule. Hydrogen bonds of the type N–H...O give rise to a layer motif parallel to (001).

Subjects by Vocabulary

Library of Congress Subject Headings: lcsh:Chemistry lcsh:QD1-999

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