Quantum Chemical and FTIR Spectroscopic Studies on the Linkage Isomerism of Carbon Monoxide in Alkali-Metal-Exchanged Zeolites: A Review of Current Research

Other literature type, Article English OPEN
E. Garrone; A. A. Tsyganenko; G. Turnes Palomino; C. Otero Areán;
  • Publisher: MDPI AG
  • Journal: International Journal of Molecular Sciences (issn: 1422-0067)
  • Related identifiers: doi: 10.3390/i3070764
  • Subject: Chemistry | Alkali metal carbonyls | Linkage isomerism | Zeolites | QD1-999 | FTIR spectroscopy | CO adsorption | Biology (General) | QH301-705.5

Abstract: When adsorbed (at a low temperature) on alkali-metal-exchanged zeolites, CO forms both M(CO)+ and M(OC)+ carbonyl species with the extra-framework alkali-metal cation of the zeolite. Both quantum chemical and experimental results show that C-bondend adducts ar... View more
  • References (40)
    40 references, page 1 of 4

    1. Cohen de Lara, E.; Nguyen Tan, T. Potential energy of a molecule adsorbed in synthetic zeolites. Application to the analysis of infrared spectra. 1. Electrostatic field in the zeolites NaA and CaA. J. Phys. Chem. 1976, 80, 1917-1921.

    2. Otero Areán, C. Zeolites and intrazeolite chemistry: insights from infrared spectroscopy. Comments Inorg. Chem. 2000, 22, 241-273.

    3. Makarova, M. A.; Al-Ghefaili, K. M.; Dwyer, J. Brønsted acid strength in US-Y: FTIR study of CO adsorption. J. Chem. Soc. Faraday Trans. 1994, 90, 383-386.

    4. Gruver, V.; Fripiat, J. J. Lewis acid sites and surface aluminum in aluminas and mordenites: an infrared study of CO chemisorption. J. Phys. Chem. 1994, 98, 8549-8554.

    5. Bordiga, S.; Garrone, E.; Lamberti, C.; Zecchina, A.; Otero Areán, C.; Kazansky, V. B.; Kustov, L. M. Comparative IR spectroscopic study of low temperature H2 and CO adsorption on Na zeolites. J. Chem. Soc. Faraday Trans. 1994, 90, 3367-3372.

    6. Wakabayashi, F.; Kondo, J. N.; Domen, K.; Hirose, C. Direct comparison of N2 and CO as IR spectrocopic probes of acid sites in H-ZSM-5 zeolite. J. Phys. Chem. 1995, 99, 10573-10580.

    7. Borovkov, V. Yu.; Karge, H. G. Use of combination modes and overtones of metal carbonyls for the IR study of cation states in zeolites. J. Chem. Soc. Faraday Trans. 1995, 91, 2035-2039.

    8. Lercher, J. A.; Gründling, C.; Eder-Mirth, G. Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules. Catal. Today 1996, 27, 353-376.

    9. Zecchina, A.; Otero Areán, C. Diatomic molecular probes for Mid-IR studies of zeolites. Chem. Soc. Rev. 1996, 25, 187-197.

    10. Lavalley, J. C. Infrared spectrometric studies of the surface basicity of metal oxides and zeolites using adsorbed probe molecules. Catal. Today 1996, 27, 377-401.

  • Metrics
    No metrics available
Share - Bookmark