Bimacrocyclic concave N-heterocyclic carbenes (NHCs): synthesis, structure, and application in catalyses

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Lüning , Ulrich; Winkelmann , Ole;
(2009)
  • Publisher: Taylor & Francis: STM, Behavioural Science and Public Health Titles
  • Related identifiers: doi: 10.1080/10610270802468413
  • Subject: Physical Sciences

International audience; Imidazolinium moieties have been incorporated into bimacrocycles to generate precursors for concave N-heterocyclic carbenes (NHCs). Starting from 2-nitroresorcinol and alkenols, symmetric concave imidazolinium salts 1 were obtained. Bimacrocycliz... View more
  • References (3)

    (a) Hadei, N.; Kantchev, E.A.B.; O´Brien, C.J.; Organ, M.G. J. Org. Chem. 2005, 8503-8507. P

    (b) Paczal, A.; Bényei, A.; Kotschy, A. J. Org. Chem. 2006, 71, 5969-5979.

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    1a18 Protein Data Bank
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