Diastereoselectivity in the reduction of bicyclic enones with hindered hydrides

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Andreza C. Camozzato; Beatriz S. M. Tenius; Eduardo R. de Oliveira; Cláudio Viegas Jr.; Maurício M. Victor; Leandro G. da Silveira;

<abstract language="eng">Reduction of five substituted octalones employing lithium tri-sec-butylborohydride (L-selectride®) in THF and ethyl ether led to allylic alcohols with moderate diastereoselectivity. The stereoselectivity of addition of bulky hydrides showed to b... View more