Nonheme oxoiron(IV) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity

Article, Other literature type English OPEN
Wang, Dong; Ray, Kallol; Collins, Michael J.; Farquhar, Erik R.; Frisch, Jonathan R.; Gómez Martín, Laura; Jackson, Timothy A.; Kerscher, Marion; Waleska, Arkadius; Comba, Peter; Costas Salgueiro, Miquel; Que, Lawrence;

Oxoiron(IV) species have been found to act as the oxidants in the catalytic cycles of several mononuclear nonheme iron enzymes that activate dioxygen. To gain insight into the factors that govern the oxidative reactivity of such complexes, a series of five synthetic S =... View more