Dielectric relaxations in poly(glycidyl phenyl ether): Effects of microstructure and cyclic topology

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Gambino, Thomas; Martínez de Ilarduya Sáez de Asteasu, Domingo Antxon; Alegría, Angel; Barroso Burjans, Fabienne;
  • Publisher: American Chemical Society (ACS)
  • Related identifiers: doi: 10.1021/acs.macromol.5b02687
  • Subject: Dielectric relaxations | NMR | microstructure | :Enginyeria química [Àrees temàtiques de la UPC] | Polimerització -- Propietats elèctriques | Polymerization--Electric properties | Poly(glycidyl phenyl ether)

Cyclic and linear, isoregic and aregic, and isotactic and atactic poly(glycidyl phenyl ether) (PGPE) with molecular weights up to Mw = 5.5 kg/mol are synthesized by ring-opening polymerization of glycidyl phenyl ether. Initiation with tetrabutylammonium fluoride leads t... View more
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