Synthesis of Mixed Carbonates via a Three-Component Coupling of Alcohols, CO2, and Alkyl Halides in the Presence of K2CO3 and Tetrabutylammonium Iodide

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Yu-Mei Shen; Min Shi;
(2002)
  • Publisher: Molecular Diversity Preservation International
  • Journal: Molecules, volume 7, issue 4, pages 386-393 (issn: 1420-3049, eissn: 1420-3049)
  • Publisher copyright policies & self-archiving
  • Identifiers: doi: 10.3390/70400386, pmc: PMC6146476
  • Subject: tetrabutylammonium iodide (TBAI) | Organic chemistry | QD241-441 | potassium carbonate | alcohols | sodium carbonate | carbonates | Article
    mesheuropmc: food and beverages

Various mixed carbonates can be conveniently prepared in good yields using the corresponding alcohols, alkyl halides under CO2 atmosphere in the presence of potassium carbonate or sodium carbonate and tetrabutylammonium iodide.
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