Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?

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Gustavsson , T.; Coto , P.-B.; Serrano-Andres , L.; Fujiwara , Taiga; Lim , E.-C.;
  • Publisher: American Institute of Physics
  • Journal: JOURNAL OF CHEMICAL PHYSICS (issn: 0021-9606)
  • Related identifiers: doi: 10.1063/1.3173609
  • Subject: visible spectra | UNESCO::FÍSICA::Química física | [CHIM.THEO] Chemical Sciences/Theoretical and/or physical chemistry | [ CHIM.THEO ] Chemical Sciences/Theoretical and/or physical chemistry | Charge exchange ; Fluorescence ; Organic compounds ; Spectrochemical analysis ; Time resolved spectra ; Visible spectra | charge exchange | fluorescence | organic compounds | spectrochemical analysis | time resolved spectra

International audience; We present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) s... View more