Synthesis of Fluorinated Amphiphilic Block Copolymers Based on PEGMA, HEMA, and MMA via ATRP and CuAAC Click Chemistry

Article English OPEN
Fatime Eren Erol; Deniz Sinirlioglu; Sedat Cosgun; Ali Ekrem Muftuoglu;
  • Publisher: Hindawi Limited
  • Journal: International Journal of Polymer Science (issn: 1687-9422, eissn: 1687-9430)
  • Related identifiers: doi: 10.1155/2014/464806
  • Subject: TP1-1185 | Chemical technology | Article Subject

Synthesis of fluorinated amphiphilic block copolymers via atom transfer radical polymerization (ATRP) and Cu(I) catalyzed Huisgen 1,3-dipolar cycloaddition (CuAAC) was demonstrated. First, a PEGMA and MMA based block copolymer carrying multiple side-chain acetylene moie... View more
  • References (44)
    44 references, page 1 of 5

    Jiang, B., Zhang, L., Shi, J., Zhou, S., Liao, B., Liu, H., Zhen, J., Pang, H.. Synthesis, characterization and bulk properties of well-defined poly(hexafluorobutyl methacrylate)-block-poly(glycidyl methacrylate) via consecutive ATRP. Journal of Fluorine Chemistry. 2013; 153: 74-81

    Krafft, M. P.. Controlling phospholipid self-assembly and film properties using highly fluorinated components—fluorinated monolayers, vesicles, emulsions and microbubbles. Biochimie. 2012; 94 (1): 11-25

    Amado, E., Kressler, J.. Triphilic block copolymers with perfluorocarbon moieties in aqueous systems and their biochemical perspectives. Soft Matter. 2011; 7 (16): 7144-7149

    Nakahara, H., Tsuji, M., Sato, Y., Krafft, M. P., Shibata, O.. Langmuir monolayer miscibility of single-chain partially fluorinated amphiphiles with tetradecanoic acid. Journal of Colloid and Interface Science. 2009; 337 (1): 201-210

    Broniatowski, M., Dynarowicz-Łatka, P.. Semifluorinated alkanes—primitive surfactants of fascinating properties. Advances in Colloid and Interface Science. 2008; 138 (2): 63-83

    Krafft, M. P.. Fluorocarbons and fluorinated amphiphiles in drug delivery and biomedical research. Advanced Drug Delivery Reviews. 2001; 47 (2-3): 209-228

    Goli, K. K., Rojas, O. J., Genzer, J.. Formation and antifouling properties of amphiphilic coatings on polypropylene fibers. Biomacromolecules. 2012; 13 (11): 3769-3779

    Peng, H., Thurecht, K. J., Blakey, I., Taran, E., Whittaker, A. K.. Effect of solvent quality on the solution properties of assemblies of partially fluorinated amphiphilic diblock copolymers. Macromolecules. 2012; 45 (21): 8681-8690

    Scholtysek, P., Li, Z., Kressler, J., Blume, A.. Interactions of DPPC with semitelechelic poly(glycerol methacrylate)s with perfluoroalkyl end groups. Langmuir. 2012; 28 (44): 15651-15662

    Zhao, Z., Ni, H., Han, Z., Jiang, T., Xu, Y., Lu, X., Ye, P.. Effect of surface compositional heterogeneities and microphase segregation of fluorinated amphiphilic copolymers on antifouling performance. ACS Applied Materials and Interfaces. 2013; 5 (16): 7808-7818

  • Related Research Results (1)
  • Metrics
    No metrics available
Share - Bookmark