Investigation by raman spectroscopy of the decomposition process of HKUST-1 upon exposure to air

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Michela Todaro; Antonino Alessi; Luisa Sciortino; Simonpietro Agnello; Marco Cannas; Franco Mario Gelardi; Gianpiero Buscarino;

We report an experimental investigation by Raman spectroscopy of the decomposition process of Metal-Organic Framework (MOF) HKUST-1 upon exposure to air moisture (T=300 K, 70% relative humidity). The data collected here are compared with the indications obtained from a ... View more
  • References (19)
    19 references, page 1 of 2

    Furukawa, H., Cordova, K. E., O'Keeffe, M., Yaghi, O. M.. The chemistry and applications of metal-organic frameworks. Science . 2013; 341 (6149): 1-12

    Rowsell, J. L. C., Yaghi, O. M.. Metal-organic frameworks: a new class of porous materials. Microporous and Mesoporous Materials . 2004; 73 (1-2): 3-14

    Canivet, J., Fateeva, A., Guo, Y., Coasne, B., Farrusseng, D.. Water adsorption in MOFs: fundamentals and applications. Chemical Society Reviews . 2014; 43 (16): 5594-5617

    Sciortino, L., Alessi, A., Messina, F., Buscarino, G., Gelardi, F. M.. Structure of the FeBTC metal-organic framework: a model based on the local environment study. The Journal of Physical Chemistry C . 2015; 119 (14): 7826-7830

    Chui, S. S.-Y., Lo, S. M.-F., Charmant, J. P. H., Orpen, A. G., Williams, I. D.. A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n. Science . 1999; 283 (5405): 1148-1150

    Li, J.-R., Kuppler, R. J., Zhou, H.-C.. Selective gas adsorption and separation in metal-organic frameworks. Chemical Society Reviews . 2009; 38 (5): 1477-1504

    Lin, K.-S., Adhikari, A. K., Ku, C.-N., Chiang, C.-L., Kuo, H.. Synthesis and characterization of porous HKUST-1 metal organic frameworks for hydrogen storage. International Journal of Hydrogen Energy . 2012; 37 (18): 13865-13871

    Liu, Y., Brown, C. M., Neumann, D. A., Peterson, V. K., Kepert, C. J.. Inelastic neutron scattering of H2 adsorbed in HKUST-1. Journal of Alloys and Compounds . 2007; 446-447: 385-388

    Getzschmann, J., Senkovska, I., Wallacher, D., Tovar, M., Fairen-Jimenez, D., Düren, T., Van Baten, J. M., Krishna, R., Kaskel, S.. Methane storage mechanism in the metal-organic framework Cu3(btc)2: an in situ neutron diffraction study. Microporous and Mesoporous Materials . 2010; 136 (1–3): 50-58

    Gul-E-Noor, F., Michel, D., Krautscheid, H., Haase, J., Bertmer, M.. Time dependent water uptake in Cu3(btc)2 MOF: identification of different water adsorption states by 1H MAS NMR. Microporous and Mesoporous Materials . 2013; 180: 8-13

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