publication . Other literature type . Article . 2017 . Embargo end date: 10 Apr 2017

Photon Reabsorption in Mixed CsPbCl3:CsPbI3 Perovskite Nanocrystal Films for Light-Emitting Diodes

Davis, NJLK; De La Peña, FJ; Tabachnyk, M; Richter, JM; Lamboll, Robin; Booker, Edward; Wisnivesky Rocca Rivarola, F; Griffiths, James; Ducati, Caterina; Menke, Stephen; ...
Open Access English
  • Published: 09 Feb 2017
  • Publisher: Apollo - University of Cambridge Repository
  • Country: United Kingdom
Abstract
Cesium lead halide nanocrystals, CsPbX$_{3}$ (X = Cl, Br, I), exhibit photoluminescence quantum efficiencies approaching 100% without the core-shell structures usually used in conventional semiconductor nanocrystals. These high photoluminescence efficiencies make these crystals ideal candidates for light-emitting diodes (LEDs). However, because of the large surface area to volume ratio, halogen exchange between perovskite nanocrystals of different compositions occurs rapidly, which is one of the limiting factors for white-light applications requiring a mixture of different crystal compositions to achieve a broad emission spectrum. Here, we use mixtures of chlori...
Subjects
free text keywords: General Energy, Physical and Theoretical Chemistry, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Chemistry, Photoluminescence, Inorganic chemistry, Crystal, Light-emitting diode, law.invention, law, Perovskite, chemistry.chemical_compound, Diode, Nanocrystal, Halogen, Halide, Article
Funded by
RCUK| Cambridge NanoScience through Engineering to Application Doctoral Training Centre: Assembly of Functional NanoMaterials and NanoDevices, RCUK| Control of spin and coherence in electronic excitations in organic and hybrid organic/inorganic semiconductor structures
Project
  • Funder: Research Council UK (RCUK)
  • Project Code: EP/M005143/1
  • Funding stream: EPSRC
,
EC| PHOTO-EM
Project
PHOTO-EM
Solar cells at the nanoscale: imaging active photoelectrodes in the transmission electron microscope.
  • Funder: European Commission (EC)
  • Project Code: 259619
  • Funding stream: FP7 | SP2 | ERC
,
EC| ESTEEM 2
Project
ESTEEM 2
Enabling Science and Technology through European Electron Microscopy
  • Funder: European Commission (EC)
  • Project Code: 312483
  • Funding stream: FP7 | SP4 | INFRA
50 references, page 1 of 4

Kojima A.; Teshima K.; Shirai Y.; Miyasaka T.Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells. J. Am. Chem. Soc.2009, 131, 6050–6051. 10.1021/ja809598r.19366264 [OpenAIRE] [PubMed] [DOI]

Lee M.; Teuscher J.; Miyasaka T.; Murakami T. N.; Snaith H. J.Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites. Science 2012, 338, 643–647. 10.1126/science.1228604.23042296 [OpenAIRE] [PubMed] [DOI]

Burschka J.; Pellet N.; Moon S.-J.; Humphry-Baker R.; Gao P.; Nazeeruddin M. K.; Grätzel M.Sequential Deposition as a Route to High-Performance Perovskite-Sensitized Solar Cells. Nature 2013, 499, 316–319. 10.1038/nature12340.23842493 [OpenAIRE] [PubMed] [DOI]

Nie W.; Tsai H.; Asadpour R.High-Efficiency Solution-Processed Perovskite Solar Cells with Millimeter-Scale Grains. Science 2015, 347, 522–525.25635093 [PubMed]

Stranks S.; Eperon G.; Grancini G.; Menelaou C.; Alcocer M. J. P.; Leijtens T.; Herz L. M.; Petrozza A.; Snaith H. J.Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber. Science 2013, 342, 341–344. 10.1126/science.1243982.24136964 [OpenAIRE] [PubMed] [DOI]

Xing G.; Mathews N.; Sun S.; Lim S.; Lam Y. M.; Gratzel M.; Mhaisalkar S.; Sum T. C.Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3. Science 2013, 342, 344–347. 10.1126/science.1243167.24136965 [OpenAIRE] [PubMed] [DOI]

Dong Q.; Fang Y.; Shao Y.; Mulligan P.; Qiu J.; Cao L.; Huang J.Ele ctron-Hole Diffusion Lengths > 175 um in Solution-Grown CH 3 NH 3 PbI 3 Single Crystals. Science 2015, 347, 967–970. 10.1126/science.aaa5760.25636799 [OpenAIRE] [PubMed] [DOI]

Tan Z.-K.; Moghaddam R. S.; Lai M. L.; Docampo P.; Higler R.; Deschler F.; Price M.; Sadhanala A.; Pazos L. M.; Credgington D.; et al. Bright Light-Emitting Diodes Based on Organometal Halide Perovskite. Nat. Nanotechnol.2014, 9, 687–692. 10.1038/nnano.2014.149.25086602 [OpenAIRE] [PubMed] [DOI]

Zhang W.; Anaya M.; Lozano G.; Calvo M. E.; Johnston M. B.; Míguez H.; Snaith H. J.Highly Efficient Perovskite Solar Cells with Tunable Structural Color. Nano Lett.2015, 15, 1698–1702. 10.1021/nl504349z.25650872 [OpenAIRE] [PubMed] [DOI]

Xing G.; Mathews N.; Lim S. S.; Yantara N.; Liu X.; Sabba D.; Grätzel M.; Mhaisalkar S.; Sum T. C.Low-Temperature Solution-Processed Wavelength-Tunable Perovskites for Lasing. Nat. Mater.2014, 13, 476–480. 10.1038/nmat3911.24633346 [PubMed] [DOI]

Filip M. R.; Eperon G. E.; Snaith H. J.; Giustino F.Steric Engineering of Metal-Halide Perovskites with Tunable Optical Band Gaps. Nat. Commun.2014, 5, 5757–5766. 10.1038/ncomms6757.25502506 [OpenAIRE] [PubMed] [DOI]

Pazos-Outón L. M.; Szumilo M.; Lamboll R.; Richter J. M.; Crespo-Quesada M.; Abdi-Jalebi M.; Beeson H. J.; Vrucinic M.; Alsari M.; Snaith H. J.; et al. Photon Recycling in Lead Iodide Perovskite Solar Cells. Science 2016, 351, 1430–1433. 10.1126/science.aaf1168.27013728 [OpenAIRE] [PubMed] [DOI]

Green M. A.; Ho-Baillie A.; Snaith H. J.The Emergence of Perovskite Solar Cells. Nat. Photonics 2014, 8, 506–514. 10.1038/nphoton.2014.134. [OpenAIRE] [DOI]

Park N.-G.Organometal Perovskite Light Absorbers toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell. J. Phys. Chem. Lett.2013, 4, 2423–2429. 10.1021/jz400892a. [OpenAIRE] [DOI]

Zhou H.; Chen Q.; Li G.; Luo S.; Song T.-b.; Duan H.-S.; Hong Z.; You J.; Liu Y.; Yang Y.Interface Engineering of Highly Efficient Perovskite Solar Cells. Science 2014, 345 (6196), 542–546. 10.1126/science.1254050.25082698 [OpenAIRE] [PubMed] [DOI]

50 references, page 1 of 4
Abstract
Cesium lead halide nanocrystals, CsPbX$_{3}$ (X = Cl, Br, I), exhibit photoluminescence quantum efficiencies approaching 100% without the core-shell structures usually used in conventional semiconductor nanocrystals. These high photoluminescence efficiencies make these crystals ideal candidates for light-emitting diodes (LEDs). However, because of the large surface area to volume ratio, halogen exchange between perovskite nanocrystals of different compositions occurs rapidly, which is one of the limiting factors for white-light applications requiring a mixture of different crystal compositions to achieve a broad emission spectrum. Here, we use mixtures of chlori...
Subjects
free text keywords: General Energy, Physical and Theoretical Chemistry, Electronic, Optical and Magnetic Materials, Surfaces, Coatings and Films, Chemistry, Photoluminescence, Inorganic chemistry, Crystal, Light-emitting diode, law.invention, law, Perovskite, chemistry.chemical_compound, Diode, Nanocrystal, Halogen, Halide, Article
Funded by
RCUK| Cambridge NanoScience through Engineering to Application Doctoral Training Centre: Assembly of Functional NanoMaterials and NanoDevices, RCUK| Control of spin and coherence in electronic excitations in organic and hybrid organic/inorganic semiconductor structures
Project
  • Funder: Research Council UK (RCUK)
  • Project Code: EP/M005143/1
  • Funding stream: EPSRC
,
EC| PHOTO-EM
Project
PHOTO-EM
Solar cells at the nanoscale: imaging active photoelectrodes in the transmission electron microscope.
  • Funder: European Commission (EC)
  • Project Code: 259619
  • Funding stream: FP7 | SP2 | ERC
,
EC| ESTEEM 2
Project
ESTEEM 2
Enabling Science and Technology through European Electron Microscopy
  • Funder: European Commission (EC)
  • Project Code: 312483
  • Funding stream: FP7 | SP4 | INFRA
50 references, page 1 of 4

Kojima A.; Teshima K.; Shirai Y.; Miyasaka T.Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells. J. Am. Chem. Soc.2009, 131, 6050–6051. 10.1021/ja809598r.19366264 [OpenAIRE] [PubMed] [DOI]

Lee M.; Teuscher J.; Miyasaka T.; Murakami T. N.; Snaith H. J.Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites. Science 2012, 338, 643–647. 10.1126/science.1228604.23042296 [OpenAIRE] [PubMed] [DOI]

Burschka J.; Pellet N.; Moon S.-J.; Humphry-Baker R.; Gao P.; Nazeeruddin M. K.; Grätzel M.Sequential Deposition as a Route to High-Performance Perovskite-Sensitized Solar Cells. Nature 2013, 499, 316–319. 10.1038/nature12340.23842493 [OpenAIRE] [PubMed] [DOI]

Nie W.; Tsai H.; Asadpour R.High-Efficiency Solution-Processed Perovskite Solar Cells with Millimeter-Scale Grains. Science 2015, 347, 522–525.25635093 [PubMed]

Stranks S.; Eperon G.; Grancini G.; Menelaou C.; Alcocer M. J. P.; Leijtens T.; Herz L. M.; Petrozza A.; Snaith H. J.Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber. Science 2013, 342, 341–344. 10.1126/science.1243982.24136964 [OpenAIRE] [PubMed] [DOI]

Xing G.; Mathews N.; Sun S.; Lim S.; Lam Y. M.; Gratzel M.; Mhaisalkar S.; Sum T. C.Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH 3 NH 3 PbI 3. Science 2013, 342, 344–347. 10.1126/science.1243167.24136965 [OpenAIRE] [PubMed] [DOI]

Dong Q.; Fang Y.; Shao Y.; Mulligan P.; Qiu J.; Cao L.; Huang J.Ele ctron-Hole Diffusion Lengths > 175 um in Solution-Grown CH 3 NH 3 PbI 3 Single Crystals. Science 2015, 347, 967–970. 10.1126/science.aaa5760.25636799 [OpenAIRE] [PubMed] [DOI]

Tan Z.-K.; Moghaddam R. S.; Lai M. L.; Docampo P.; Higler R.; Deschler F.; Price M.; Sadhanala A.; Pazos L. M.; Credgington D.; et al. Bright Light-Emitting Diodes Based on Organometal Halide Perovskite. Nat. Nanotechnol.2014, 9, 687–692. 10.1038/nnano.2014.149.25086602 [OpenAIRE] [PubMed] [DOI]

Zhang W.; Anaya M.; Lozano G.; Calvo M. E.; Johnston M. B.; Míguez H.; Snaith H. J.Highly Efficient Perovskite Solar Cells with Tunable Structural Color. Nano Lett.2015, 15, 1698–1702. 10.1021/nl504349z.25650872 [OpenAIRE] [PubMed] [DOI]

Xing G.; Mathews N.; Lim S. S.; Yantara N.; Liu X.; Sabba D.; Grätzel M.; Mhaisalkar S.; Sum T. C.Low-Temperature Solution-Processed Wavelength-Tunable Perovskites for Lasing. Nat. Mater.2014, 13, 476–480. 10.1038/nmat3911.24633346 [PubMed] [DOI]

Filip M. R.; Eperon G. E.; Snaith H. J.; Giustino F.Steric Engineering of Metal-Halide Perovskites with Tunable Optical Band Gaps. Nat. Commun.2014, 5, 5757–5766. 10.1038/ncomms6757.25502506 [OpenAIRE] [PubMed] [DOI]

Pazos-Outón L. M.; Szumilo M.; Lamboll R.; Richter J. M.; Crespo-Quesada M.; Abdi-Jalebi M.; Beeson H. J.; Vrucinic M.; Alsari M.; Snaith H. J.; et al. Photon Recycling in Lead Iodide Perovskite Solar Cells. Science 2016, 351, 1430–1433. 10.1126/science.aaf1168.27013728 [OpenAIRE] [PubMed] [DOI]

Green M. A.; Ho-Baillie A.; Snaith H. J.The Emergence of Perovskite Solar Cells. Nat. Photonics 2014, 8, 506–514. 10.1038/nphoton.2014.134. [OpenAIRE] [DOI]

Park N.-G.Organometal Perovskite Light Absorbers toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell. J. Phys. Chem. Lett.2013, 4, 2423–2429. 10.1021/jz400892a. [OpenAIRE] [DOI]

Zhou H.; Chen Q.; Li G.; Luo S.; Song T.-b.; Duan H.-S.; Hong Z.; You J.; Liu Y.; Yang Y.Interface Engineering of Highly Efficient Perovskite Solar Cells. Science 2014, 345 (6196), 542–546. 10.1126/science.1254050.25082698 [OpenAIRE] [PubMed] [DOI]

50 references, page 1 of 4
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publication . Other literature type . Article . 2017 . Embargo end date: 10 Apr 2017

Photon Reabsorption in Mixed CsPbCl3:CsPbI3 Perovskite Nanocrystal Films for Light-Emitting Diodes

Davis, NJLK; De La Peña, FJ; Tabachnyk, M; Richter, JM; Lamboll, Robin; Booker, Edward; Wisnivesky Rocca Rivarola, F; Griffiths, James; Ducati, Caterina; Menke, Stephen; ...