Activation Volumes for Peroxodisulphate Oxidation of Low-spin Iron(II) Complexes in Aqueous Salt Solutions

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Benko, Ján; Burgess, John; López Cornejo, María Pilar; Vollárová, Olga;
  • Publisher: Croatian Chemical Society
  • Journal: volume 74,issue 3issn: 0011-1643, eissn: 1334-417X
  • Publisher copyright policies & self-archiving
  • Subject: iron(II)-2,2'-bipyridyl-cyanide complexes; peroxodisulphate oxidation; activation volumes | Iron(II)-2,2′-bipyridyl-cyanide complexes | Peroxodisulphate oxidation

Activation volumes are reported for peroxodisulphate oxidation of the four complexes of the Fe2+-2,2'-bipyridyl-cyanide sequence, viz. [Fe(bipy)3]2+, [Fe(bipy)2(CN)2], [Fe(bipy)(CN)4]2- and [Fe(CN)6]4- (abbr. bipy for 2,2'-bipyridyl), in aqueous Solutions of a selection... View more
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