On the mechanism of photocatalytic reactions with eosin Y

Article English OPEN
Michal Majek; Fabiana Filace; Axel Jacobi von Wangelin;
  • Publisher: Beilstein-Institut
  • Journal: Beilstein Journal of Organic Chemistry,volume 10,pages981-989 (issn: 1860-5397, eissn: 1860-5397)
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  • Related identifiers: doi: 10.3762/bjoc.10.97, pmc: PMC4077370
  • Subject: organocatalysis | Chemistry | Q | Full Research Paper | Organic Chemistry | QD241-441 | Science | quantum yields | photoredox catalysis | visible light | mechanism | photocatalysis

Summary A combined spectroscopic, synthetic, and apparative study has allowed a more detailed mechanistic rationalization of several recently reported eosin Y-catalyzed aromatic substitutions at arenediazonium salts. The operation of rapid acid–base equilibria, direct p... View more
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