Synthesis of Ethylene or Propylene/1,3-Butadiene Copolymers Possessing Pendant Vinyl Groups with Virtually No Internal Olefins

Article, Other literature type English OPEN
Michiue, Kenji; Mitani, Makoto; Fujita, Terunori;
(2015)
  • Publisher: Multidisciplinary Digital Publishing Institute
  • Journal: Catalysts (issn: 2073-4344)
  • Related identifiers: doi: 10.3390/catal5042001
  • Subject: Chemistry | C2-symmetric zirconocene | TP1-1185 | QD1-999 | insertion mode | vinylenes | Chemical technology | vinyl groups | <i>C</i><sub>2</sub>-symmetric zirconocene | 1,3-butadiene | internal olefins

In general, ethylene/1,3-butadiene copolymerizations provides copolymers possessing both pendant vinyls and vinylenes as olefinic moieties. We, at MCI, studied the substituent effects of C2-symmetric zirconocene complexes, rac-[Me2Si(Indenyl’)2]ZrCl2 (Indenyl’ = generic... View more
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