publication . Other literature type . Article . 2016

english

S. A. Rane;
Open Access
  • Published: 17 Apr 2016
  • Publisher: Croatian Society of Chemical Engineers/HDKI
Abstract
Recently, biomass-derived energy has been receiving more and more attention due to the depletion of conventional fossil sources at a faster rate, as well as major environmental issues.1 Biodiesel obtained by transesterification of vegetable oils and animal fats provides an alternative fuel option for the future.2 Transesterification of oils and animal fats produce glycerol in large excess (10 kg glycerol/90 kg of biodiesel) as a byproduct.3 In recent decades, with the rapid development of the biodiesel industry, glycerol has been oversupplied in the market, resulting in a significant decrease in the price of glycerol. Therefore, it is essential to develop a new ...
37 references, page 1 of 3

1. Bozell, J., Connecting biomass and petroleum processing with a chemical Bridge, Science 329 (2010) 522. doi: http://dx.doi.org/10.1126/science.1191662

2. Xia, S., Zheng, L., Wang, L., Chena, P., Hou, Z., Hydrogen-free synthesis of 1,2-propanediol from glycerol over Cu-Mg-Al catalysts, RSC Adv. 3 (2013) 16569. doi: http://dx.doi.org/10.1039/c3ra42543f

3. Goncalves, V., Pinto, B., Silva, J., Mota, C., Acetylation of glycerol catalyzed by different solid acids, Catal. Today 133-135 (2008) 673. doi: http://dx.doi.org/10.1016/j.cattod.2007.12.037

4. Tan, H., Aziz, A., Aroua, M., Glycerol production and its applications as a raw material: A review, Renew. Sust. Energ. Rev. 27 (2013) 118. doi: http://dx.doi.org/10.1016/j.rser.2013.06.035

5. Johnsona, D., Taconi, K., The Glycerin glut: options for the value-added conversion of crude glycerol resulting from biodiesel production, Environ. Progress. 26 (2007) 338. doi: http://dx.doi.org/10.1002/ep.10225 [OpenAIRE]

6. Klepacova, K., Mravec, D., Kaszonyi, A., Bajus M., Etherification of glycerol and ethylene glycol by isobutylene, Appl. Catal. A: Gen. 328 (2007) 1. doi: http://dx.doi.org/10.1016/j.apcata.2007.03.031 [OpenAIRE]

7. Melero, J., Grieken, R., Morale, G., Paniagua, M., Acidic mesoporous silica for the acetylation of glycerol: synthesis of bioadditives to petrol fuel, Energy and Fuels 21 (2007) 1782. doi: http://dx.doi.org/10.1021/ef060647q [OpenAIRE]

8. Ferreira, P., Fonseca, I., Ramos, A., Vital, J., Castanheiro, J., Glycerol acetylation over dodecatungstophosphoric acid immobilized into a silica matrix as catalyst, Appl. Catal. B: Environ. 91 (2009) 416. doi: http://dx.doi.org/10.1016/j.apcatb.2009.06.009

9. Dosuna-Rodriguez, I., Adriany, C., Gaigneaux, E., Glycerol acetylation on sulphated zirconia in mild conditions, Catal. Today 167 (2011) 56. doi: http://dx.doi.org/10.1016/j.cattod.2010.11.057

10. Dosuna-Rodriguez, I., Gaigneaux, E., Glycerol acetylation catalysed by ion exchange resins, Catal. Today 195 (2012) 14. doi: http://dx.doi.org/10.1016/j.cattod.2012.04.031

11. Jagadeeswaraiah, K., Balaraju, M., Sai Prasad, P., Lingaiah, N., Selective esterification of glycerol to bioadditives over heteropoly tungstate supported on Cs-containing zirconia catalysts, Appl. Catal. A: Gen. 386 (2010) 166. doi: http://dx.doi.org/10.1016/j.apcata.2010.07.046

12. Ferreira, P., Fonseca, I., Ramos, A., Vital, J., Castanheiro, J., Acetylation of glycerol over heteropolyacids supported on activated carbon, Catal. Commun. 12 (2011) 573. doi: http://dx.doi.org/10.1016/j.catcom.2010.11.022

13. Liao, X., Zhu, Y., Wang, S., Li, Y., Producing triacetylglycerol with glycerol by two steps: Esterification and acetylation, Fuel Proc. Technol. 90 (2009) 988. doi: http://dx.doi.org/10.1016/j.fuproc.2009.03.015

14. Guerrero-Perez, M., Rosas, J., Bedia, J., Rodriguez-Mirasol, J., Cordero, T., Recent Inventions in Glycerol Transformations and Processing, Recent Patents on Chem. Engg. 2 (2009) 11. doi: http://dx.doi.org/10.2174/2211334710902010011

15. Granados, M., Alba-Rubio, A., Vila, F., Alonso, D., Mariscal, R., Surface chemical promotion of Ca oxide catalysts in biodiesel production reaction by the addition of monoglycerides, diglycerides and glycerol, J. Catal. 276 (2010) 229. doi: http://dx.doi.org/10.1016/j.jcat.2010.09.016

37 references, page 1 of 3
Abstract
Recently, biomass-derived energy has been receiving more and more attention due to the depletion of conventional fossil sources at a faster rate, as well as major environmental issues.1 Biodiesel obtained by transesterification of vegetable oils and animal fats provides an alternative fuel option for the future.2 Transesterification of oils and animal fats produce glycerol in large excess (10 kg glycerol/90 kg of biodiesel) as a byproduct.3 In recent decades, with the rapid development of the biodiesel industry, glycerol has been oversupplied in the market, resulting in a significant decrease in the price of glycerol. Therefore, it is essential to develop a new ...
37 references, page 1 of 3

1. Bozell, J., Connecting biomass and petroleum processing with a chemical Bridge, Science 329 (2010) 522. doi: http://dx.doi.org/10.1126/science.1191662

2. Xia, S., Zheng, L., Wang, L., Chena, P., Hou, Z., Hydrogen-free synthesis of 1,2-propanediol from glycerol over Cu-Mg-Al catalysts, RSC Adv. 3 (2013) 16569. doi: http://dx.doi.org/10.1039/c3ra42543f

3. Goncalves, V., Pinto, B., Silva, J., Mota, C., Acetylation of glycerol catalyzed by different solid acids, Catal. Today 133-135 (2008) 673. doi: http://dx.doi.org/10.1016/j.cattod.2007.12.037

4. Tan, H., Aziz, A., Aroua, M., Glycerol production and its applications as a raw material: A review, Renew. Sust. Energ. Rev. 27 (2013) 118. doi: http://dx.doi.org/10.1016/j.rser.2013.06.035

5. Johnsona, D., Taconi, K., The Glycerin glut: options for the value-added conversion of crude glycerol resulting from biodiesel production, Environ. Progress. 26 (2007) 338. doi: http://dx.doi.org/10.1002/ep.10225 [OpenAIRE]

6. Klepacova, K., Mravec, D., Kaszonyi, A., Bajus M., Etherification of glycerol and ethylene glycol by isobutylene, Appl. Catal. A: Gen. 328 (2007) 1. doi: http://dx.doi.org/10.1016/j.apcata.2007.03.031 [OpenAIRE]

7. Melero, J., Grieken, R., Morale, G., Paniagua, M., Acidic mesoporous silica for the acetylation of glycerol: synthesis of bioadditives to petrol fuel, Energy and Fuels 21 (2007) 1782. doi: http://dx.doi.org/10.1021/ef060647q [OpenAIRE]

8. Ferreira, P., Fonseca, I., Ramos, A., Vital, J., Castanheiro, J., Glycerol acetylation over dodecatungstophosphoric acid immobilized into a silica matrix as catalyst, Appl. Catal. B: Environ. 91 (2009) 416. doi: http://dx.doi.org/10.1016/j.apcatb.2009.06.009

9. Dosuna-Rodriguez, I., Adriany, C., Gaigneaux, E., Glycerol acetylation on sulphated zirconia in mild conditions, Catal. Today 167 (2011) 56. doi: http://dx.doi.org/10.1016/j.cattod.2010.11.057

10. Dosuna-Rodriguez, I., Gaigneaux, E., Glycerol acetylation catalysed by ion exchange resins, Catal. Today 195 (2012) 14. doi: http://dx.doi.org/10.1016/j.cattod.2012.04.031

11. Jagadeeswaraiah, K., Balaraju, M., Sai Prasad, P., Lingaiah, N., Selective esterification of glycerol to bioadditives over heteropoly tungstate supported on Cs-containing zirconia catalysts, Appl. Catal. A: Gen. 386 (2010) 166. doi: http://dx.doi.org/10.1016/j.apcata.2010.07.046

12. Ferreira, P., Fonseca, I., Ramos, A., Vital, J., Castanheiro, J., Acetylation of glycerol over heteropolyacids supported on activated carbon, Catal. Commun. 12 (2011) 573. doi: http://dx.doi.org/10.1016/j.catcom.2010.11.022

13. Liao, X., Zhu, Y., Wang, S., Li, Y., Producing triacetylglycerol with glycerol by two steps: Esterification and acetylation, Fuel Proc. Technol. 90 (2009) 988. doi: http://dx.doi.org/10.1016/j.fuproc.2009.03.015

14. Guerrero-Perez, M., Rosas, J., Bedia, J., Rodriguez-Mirasol, J., Cordero, T., Recent Inventions in Glycerol Transformations and Processing, Recent Patents on Chem. Engg. 2 (2009) 11. doi: http://dx.doi.org/10.2174/2211334710902010011

15. Granados, M., Alba-Rubio, A., Vila, F., Alonso, D., Mariscal, R., Surface chemical promotion of Ca oxide catalysts in biodiesel production reaction by the addition of monoglycerides, diglycerides and glycerol, J. Catal. 276 (2010) 229. doi: http://dx.doi.org/10.1016/j.jcat.2010.09.016

37 references, page 1 of 3
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