Homolytic cleavage of molecular oxygen by manganese porphyrins supported on Ag(111).

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Murphy, BE ; Krasnikov, SA ; Sergeeva, NN ; Cafolla, AA ; Preobrajenski, AB ; Chaika, AN ; Lübben, O ; Shvets, IV (2014)
  • Publisher: American Chemical Society

Oxygen binding and cleavage are important for both molecular recognition and catalysis. Mn-based porphyrins in particular are used as catalysts for the epoxidation of alkenes, and in this study the homolytic cleavage of O2 by a surface-supported monolayer of Mn porphyri... View more
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