publication . Article . 2017

Effective Separation of Am(III) from Cm(III) Using Modified BTPhen Ligands

Laurence M. Harwood; Ashfaq Afsar; Alyn C. Edwards; Andreas Geist; Michael J. Hudson; James Westwood; Roger C. Whitehead;
Closed Access English
  • Published: 01 Jan 2017
  • Publisher: The Japan Institute of Heterocyclic Chemistry
  • Country: United Kingdom
Abstract
Electronic modulation of CyMe4-BTPhen with 5-bromo and 5-(4-hydroxyphenyl) substituents leads to enhanced separation of Am(III) from Cm(III) over 0.1 – 3 M HNO3 (SFAm/Cm = ca. 9 at 0.1 M HNO3). In addition, substituting bromine atoms at the 5 and 6 positions of the phenanthroline backbone provides a mean of separating Am(III) from Eu(III) (SFAm/Eu = ca. 240 at 3 M HNO3).
Subjects
free text keywords: Photochemistry, Bromine, chemistry.chemical_element, chemistry, Atom, Phenanthroline, chemistry.chemical_compound, Ligand, Medicinal chemistry, Stereochemistry
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