Expanded ring carbenes - synthesis, coordination and catalysis

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Iglesias Alonso, Manuel;
  • Subject: QD

The work presented in this thesis is mainly concerned with the synthesis, metal coordination and applications of expanded (larger than five-membered) N-heterocyclic carbenes. Chapter two describes the spectroscopic and solid state properties of novel 7-membered carbenes... View more
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    11 references, page 1 of 2

    4. Complexes o f expanded-ring N-heterocyclic carb en es.....................

    4.1. Introduction...............................................................................................

    4.2. Results and discussion................................................................................

    4.2.1. Complexation o f cyclohexyl derivatives................................................................

    4.2.1.1. Synthesis o f the [Pt(7~Cy)(nbe)2] complex.........................................................

    4.2.1.2 Solid state structure o f the [Pt(7-Cy)(nbe)2] complex........................................

    4.2.1.3. Rhodium(I) and Iridium(I) COD complexes......................................................

    4.2.1.4. Solid state structures o f Rh(I) and Ir(I) COD complexes..................................

    4.2.1.5. Rhodium(I) andIridium (I) biscarbonyl complexes............................................

    4.2.1.6. Solid state structure o f Rh(I) and Ir(I) biscarbonyl complexes.........................

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