Phase evolution of C-(N)-A-S-H/N-A-S-H gel blends investigated via alkali-activation of synthetic calcium aluminosilicate precursors

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Walkley, B. ; San Nicolas, R. ; Sani, M.A. ; Rees, G.J. ; Hanna, J.V. ; van Deventer, J.S.J. ; Provis, J.L. (2016)
  • Publisher: Elsevier

Stoichiometrically-controlled alkali-activated pastes containing calcium-(sodium) aluminosilicate hydrate (C-(N)-A-S-H) and sodium aluminosilicate hydrate (N-A-S-H) gels are produced by alkali-activation of high-purity synthetic calcium aluminosilicate powders. These powders are chemically comparable to the glass in granulated blast furnace slag, but without interference from minor constituents. The physiochemical characteristics of these gels depend on precursor chemical composition. Increased Ca content of the precursor promotes formation of low-Al, high-Ca C-(N)-A-S-H with lower mean chain length as determined by quantification of solid state nuclear magnetic resonance spectra, and less formation of calcium carboaluminate ‘Alumino-ferrite mono’ (AFm) phases. Increased Al content promotes Al inclusion and reduced crosslinking within C-(N)-A-S-H, increased formation of calcium carboaluminate AFm phases, and formation of an additional N-A-S-H gel. Small changes in precursor composition can induce significant changes in phase evolution, nanostructure and physical properties, providing a novel route to understand microstructural development in alkali-activated binders and address key related durability issues.
  • References (17)
    17 references, page 1 of 2

    [1] M.C.G. Juenger, F. Winnefeld, J.L. Provis, J.H. Ideker, Advances in alternative cementitious binders, Cem Concr Res, 41 (2011) 1232-1243.

    [2] J.L. Provis, A. Palomo, C.J. Shi, Advances in understanding alkali-activated materials, Cem Concr Res, 78 (2015) 110-125.

    [3] X.-m. Cui, L.-p. Liu, G.-j. Zheng, R.-p. Wang, J.- geopolymers, J Non-Cryst Solids, 356 (2010) 72-76.

    [4] I. García- - cphee, Effect on fresh C-S-H gels of the simultaneous addition of alkali and aluminium, Cem Concr Res, 40 (2010) 27-32.

    [5] I. García- - of cementitious gels: C–S–H and N–A–S–H, J Sol-Gel Sci Technol, 45 (2008) 63-72.

    [21] R.J. Myers, S.A. Bernal, J.D. Gehman, J.S.J. van Deventer, J.L. Provis, The role of Al in cross-linking of alkali-activated slag cements, J Am Ceram Soc, 98 (2015) 996-1004.

    [22] R.J. Myers, S.A. Bernal, J.L. Provis, A thermodynamic model for C-(N-)A-S-H gel: CNASH_ss. Derivation and validation, Cem Concr Res, 66 (2014) 27-47. [36] J.L. Provis, P. Duxson, G.C. Lukey, J.S.J. van Deventer, Statistical thermodynamic model for Si/Al ordering in amorphous aluminosilicates, Chem Mater, 17 (2005) 2976-2986. [38] B. Lothenbach, G. Le Saoût, E. Gallucci, K. Scrivener, Influence of limestone on the hydration of Portland cements, Cem Concr Res, 38 (2008) 848-860. [51] S.A. Bernal, R. Mejía de Gutié incorporation on the carbonation of alkali silicate-activated slags, Cem Concr Res, 40 (2010) 898-907.

    [54] V.C. Farmer, The Infrared spectra of minerals, Mineralogical Society, London, 1974.

    [55] I.G. Richardson, The nature of C-S-H in hardened cements, Cem Concr Res, 29 (1999) 1131-1147.

    [56] A.L. Gameiro, A.S. Silva, M.d.R. Veiga, A.L. Velosa, Lime-metakaolin hydration products: A microscopy analysis, Mater Technol, 46 (2012) 145-148.

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