Hydrothermal saline promoted grafting of periodic mesoporous organic sulfonic acid silicas for sustainable FAME production

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Pirez, C. ; Tapia Reche, M. ; Lee, A.F. ; Manayil, J.C. ; dos-Santos, V.C. ; Wilson, K. (2015)

Hydrothermal saline promoted grafting of sulfonic acid groups onto SBA-15 and periodic mesoporous organic silica analogues affords solid acid catalysts with high acid site loadings (>2.5 mmol g-1 H+), ordered mesoporosity and tunable hydrophobicity. The resulting catalysts show excellent activity for fatty acid esterification and tripalmitin transesterification to methyl palmitate, with framework phenyl groups promoting fatty acid methyl esters production. (Chemical Equation Presented)
  • References (26)
    26 references, page 1 of 3

    1. Asefa T, MacLachlan MJ, Coombs N, Ozin GA (1999) Nature 402: 867. doi:http://www.nature.com/nature/journal/v402/n6764/suppinfo/4028 67a0_S1.html

    2. Su F, Guo Y (2014) Green Chemistry 16: 2934. doi:10.1039/c3gc42333f

    3. Melero JA, Iglesias J, Morales G (2009) Green Chemistry 11: 1285. doi:10.1039/b902086a

    4. Dacquin JP, Lee AF, Pirez C, Wilson K (2012) Chemical Communications 48: 212. doi:10.1039/c1cc14563k

    5. Pirez C, Caderon J-M, Dacquin J-P, Lee AF, Wilson K (2012) ACS Catalysis 2: 1607. doi:10.1021/cs300161a

    6. Dhainaut J, Dacquin J-P, Lee AF, Wilson K (2010) Green Chemistry 12: 296. doi:10.1039/b919341c

    7. aMbaraka IK, Shanks BH (2005) Journal of Catalysis 229: 365. doi:http://dx.doi.org/10.1016/j.jcat.2004.11.008; bMelero JA, Bautista LF, Morales G, Iglesias J, Sánchez-Vázquez R (2010) Chemical Engineering Journal 161: 323. doi:http://dx.doi.org/10.1016/j.cej.2009.12.037

    8. Dacquin J-P, Cross HE, Brown DR, Duren T, Williams JJ, Lee AF, Wilson K (2010) Green Chemistry 12: 1383. doi:10.1039/C0GC00045K

    9. Inagaki S, Guan S, Ohsuna T, Terasaki O (2002) Nature 416: 304. doi:http://www.nature.com/nature/journal/v416/n6878/suppinfo/4163 04a_S1.html

    10. Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O (1999) Journal of the American Chemical Society 121: 9611. doi:10.1021/ja9916658

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