publication . Article . 2011

Longer-range distances by spinning-angle-encoding solid-state NMR spectroscopy

Johanna Becker-Baldus;
Open Access
  • Published: 01 Jan 2011 Journal: Physical Chemistry Chemical Physics, volume 13, page 4,514 (issn: 1463-9076, eissn: 1463-9084, Copyright policy)
  • Publisher: Royal Society of Chemistry (RSC)
  • Country: United Kingdom
A new spinning-angle-encoding spin-echo solid-state NMR approach is used to accurately determine the\ud dipolar coupling corresponding to a C-C distance over 4 Å in a fully labelled dipeptide. The dipolar coupling\ud dependent spin-echo modulation was recorded off magic angle, switching back to the magic angle for the\ud acquisition of the free-induction decay, so as to obtain optimum sensitivity. The retention of both ideal\ud resolution and long-range distance sensitivity was achieved by redesigning a 600MHz HXMAS NMR probe\ud to provide fast angle switching during the NMR experiment: For 1.8 mm rotors, angle changes of up to ~5\ud degrees in ~10 ms were achie...
free text keywords: Physical and Theoretical Chemistry, General Physics and Astronomy, Magnetic dipole–dipole interaction, Nuclear magnetic resonance spectroscopy, Spin echo, Chemistry, Analytical chemistry, Magic angle, Spectroscopy, Inorganic chemistry, Molecular physics, Modulation, Solid-state nuclear magnetic resonance, Spinning, QC
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