Communication: Infrared spectroscopy of salt-water complexes

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Tandy, Jonathan D.; Feng, Cheng; Boatwright, Adrian; Sarma, Gautam; Sadoon, Ahmed M.; Shirley, Andrew; Rodrigues, Natercia Das Neves; Cunningham, Ethan M.; Yang, Shengfu; Ellis, Andrew M.;

To explore how the ion-pair in a single salt molecule evolves with the addition of water, infrared (IR) spectra of complexes composed of NaCl and multiple water molecules have been recorded for the first time. The NaCl(H2O)n complexes were formed and probed in liquid he... View more
  • References (27)
    27 references, page 1 of 3

    1B. E. Conway, Ionic Hydration in Chemistry and Biophysics (Elsevier Scientific Publishing Company, Amsterdam, 1981).

    2Y. Marcus, Ion Solvation (Wiley, New York, 1985).

    3J. Burgess, Ions in Solution: Basic Principles of Chemical Interactions (Ellis Horwood, New York, 1988).

    4R. S. Eisenberg, Physiology 28, 28 (2013).

    5M. Eigen and K. Z. Tamm, Elektrochemische 66, 93 (1962).

    6Y. Marcus and G. Hefter, Chem. Rev. 106, 4585 (2006).

    7A. Gutberlet, G. Schwaab, Ö Birer, M. Masia, A. Kaczmarek, H. Forbert, M. Havenith, and D. Marx, Science 324, 1545 (2009).

    8D. Skvortsov, S. J. Lee, M. Y. Choi, and A. F. Vilesov, J. Phys. Chem. A 113, 7360 (2009).

    9S. D. Flynn, D. Skvortsov, A. M. Morrison, T. Liang, M. Y. Choi, G. E. Douberly, and A. F. Vilesov, J. Phys. Chem. Lett. 1, 2233 (2010).

    10A. M. Morrison, S. D. Flynn, T. Liang, and G. E. Douberly, J. Phys. Chem. A 114, 8090 (2010).

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