Fullerene-like models for microporous carbon

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Harris, Peter J. F. (2013)

Microporous carbons are important in a wide variety of applications, ranging from pollution control to supercapacitors, yet their structure at the molecular\ud level is poorly understood. Over the years, many structural models have been put forward, but none have been entirely satisfactory in explaining the properties of the carbons. The discovery of fullerenes and fullerene-related\ud structures such as carbon nanotubes gave us a new perspective on the structure of solid carbon, and in 1997 it was suggested that microporous carbon may have a structure related to that of the fullerenes. Recently,\ud evidence in support of such a structure has been obtained using aberration-corrected transmission electron microscopy, electron energy loss spectroscopy and other techniques. This article describes the development of ideas about the structure of microporous carbon, and reviews the experimental evidence for a fullerene-related structure. Theoretical models of the structural evolution of microporous carbon are summarised, and the use of fullerene-like models to predict the adsorptive properties of microporous carbons are reviewed.
  • References (41)
    41 references, page 1 of 5

    Derbyshire F, Jagtoyen M, Thwaites M (1995) In: Patrick JW, editor Porosity in carbons: Characterization and applications. Edward Arnold, London p. 227

    Patrick JW, editor (1995) Porosity in carbons: Characterization and applications. Edward Arnold, London

    Marsh H, Rodriguez-Reinoso F (2006) Activated carbon. Elsevier, Oxford.

    12. Ban LL (1972) In: Roberts MW, Thomas JM, editors. Surface and Defect Properties of Solids, vol 1. Chemical Society, London p. 54

    13. Ban LL, Crawford D, Marsh H (1975) Journal of Applied Crystallography 8: 415

    14. Jenkins GM, Kawamura K (1971) Nature 231: 175

    15. Oberlin A (1989) In: Thrower PA, editor. Chemistry and Physics of Carbon, vol 22, Dekker, New York p. 1-143.

    20. Harris PJF (2009) Carbon nanotube science. Cambridge University Press, Cambridge

    21. Harris PJF, Tsang SC, Claridge JB, Green MLH (1994) Journal of the Chemical Society-Faraday Transactions 90: 2799

    22. Iijima S, Yudasaka M, Yamada R, Bandow S, Suenaga K, Kokai F, Takahashi K (1999) Chemical Physics Letters 309: 165

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