Carbocation/Polyol Systems as Efficient Organic Catalysts for the Preparation of Cyclic Carbonates

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Rulev, Yuri A.; Gugkaeva, Zalina T.; Lokutova, Anastasia V.; Maleev, Victor I.; Peregudov, Alexander S.; Wu, Xiao; North, Michael; Belokon, Yuri N.;
  • Subject: 2304 | 1500 | 2500 | 2100

Carbocation/polyol systems are shown to be highly efficient catalysts for the synthesis of cyclic carbonates from epoxides and carbon dioxide at 50°C and 5MPa CO2 pressure. The best activity was shown by the combination of crystal violet and 1,1'-bi-2-naphthol (BINOL), ... View more
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