Carbocation/Polyol Systems as Efficient Organic Catalysts for the Preparation of Cyclic Carbonates

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Rulev, Yuri A. ; Gugkaeva, Zalina T. ; Lokutova, Anastasia V. ; Maleev, Victor I. ; Peregudov, Alexander S. ; Wu, Xiao ; North, Michael ; Belokon, Yuri N.
  • Subject: 2304 | 1500 | 2500 | 2100

Carbocation/polyol systems are shown to be highly efficient catalysts for the synthesis of cyclic carbonates from epoxides and carbon dioxide at 50°C and 5MPa CO2 pressure. The best activity was shown by the combination of crystal violet and 1,1'-bi-2-naphthol (BINOL), ... View more
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