Modifying the product distribution of a reaction within the controlled microenvironment of a colloidosome

Article English OPEN
Mann, G.; Ellis, A.; Twyman, L.J.;
  • Publisher: American Chemical Society

A water-soluble colloidosome composed of PGMA–PS latex was used as a microcapsule to host a catalyzed oxidation reaction within its dodecane core. When compared to a control reaction a significant colloidosome effect was observed. Specifically, a 233% increase in the re... View more
  • References (7)

    1. (a) Immordino, M. L.; Dosio, F.; Cattel, L.; Stealth Liposomes: Review of The Basic Science, Rationale, and Clinical Applications, Existing and Potential. Int J Nanomedicine. 2006, 1(3): 297-315. (b) Muller, R. H.; Mader, K.; Gohla, S. Solid Lipid Nanoparticles (SLN) For Controlled Drug Delivery - A Review of the State of the Art. Eur. J. of Pharm. and Biopharm. 2000, 50, 161-77. (c) Hong; R.; Han, G.; Fernández, J. M.; Kim, B-J.; Forbes, N. S.; Rotello, V. M. Glutathione-Mediated Delivery and Release Using Monolayer Protected Nanoparticle Carriers J. Am. Chem. Soc., 2006, 128(4), 1078-79.

    2. (a) Yow, H. N.; Routh, A. F. Release Profiles of Encapsulated Actives from Colloidosomes Sintered for Various Durations. Langmuir 2009, 25, 159-66. (b) Gibbs, B. F.; Kermasha, S.; Alli, I.; Mulligan, C. N. Encapsulation in the Food Industry: a Review. Int. J. Food Sci. Nutr. 1999, 50(3), 213-24

    3. Saraf, S.; Rathi, R.; Kaur, C. D.; Saraf, S. Colloidosomes an Advanced Vesicular System in Drug Delivery. Asian J. Sci. Res. 2011, 4(1), 1-15.

    4. Pickering, S. U. Emulsions. J. Chem. Soc., Trans. 1907, 91, 2001-21.

    5. (a) Li, M;, Harbron,; R. L., Weaver, J. V. M.; Binks, B. P;. Mann, S. Electrostatically Gated Membrane Permeability in Inorganic Protocells. Nature Chem.2013, 5, 529-36. (b) Thompson, K. L.; Armes, S. P. From Well-Defined Macromonomers to Sterically-Stabilised Latexes to Covalently Cross-Linkable Colloidosomes: Exerting Control Over Multiple Length Scales. Chem. Comm. 2010, 46, 5274-76.

    6. Dinsmore, A. D.; Hsu, M. F.; Nikolaides, M. G.; Marquez, M.; Bausch, A. R.; Weitz, D. A. Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles. Science. 2002, 298, 1006-9.

    7. (a) Wu, C.; Bai, S.; Ansorge-Schumacher, M. B.; Wang, D. Nanoparticle Cages for Enzyme Catalysis in Organic Media. Adv. Mater. 2011, 23, 5694-99. (b) Buthe, A.; Kapitain, A.; Hartmeier, W.; Ansorge-Schumacher, M. B. Generation of LipaseContaining Static Emulsions in Silicone Spheres for Synthesis in Organic Media. J. Mol. Catal. B: Enzym. 2005, 35, 93-99. (c) Wu, C.-Z.; Kraume, M.; Ansorge-

  • Metrics
Share - Bookmark